天然气化工,环保,新材料,石油炼制,石油化工,精细化工

有机合成与催化，光催化合成，自由基化学，含氟化合物合成

Transition Metal Catalysis;1,2-nitrogen Migration;C-h Coupling;Ni/diboron Catalysis;Radical Relay;Beta-aminoacids;Nitrogen-centered Radicals;Arylation Reactions

1. Radical 1,4‐aryl Migration Enabled Remote Cross‐Electrophile Coupling of Α‐amino‐β‐bromo Acid Esters with Aryl Bromides
Shi Tang; Zhen-Hua Xu; Ting Liu; Shuo-Wen Wang; Jian Yu; Jian Liu; Yu Hong; Shi-Lu Chen; Jin He; Jin-Heng Li
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021

2. Radical 1,2-Nitrogen Migration Cascades of Β-Bromo Α-Amino Acid Esters to Access Β-Amino Acid Motifs Enabled by Cooperative Ni/Diboron Catalysis
Yu Hong; Zi-Cheng Liao; Jia-Jie Chen; Jian Liu; Yin-Ling Liu; Jin-Heng Li; Qing Sun; Shi-Lu Chen; Shuo-Wen Wang; Shi Tang
ACS CATALYSIS, 2024

3. Nickel-Catalyzed Radical Heck-Type C(sp3)-C(sp2) Coupling Cascades Enabled by Bromoalkane-Directed 1,4-Aryl Shift: Access to Olefinated Arylalanines.
Jian Liu; Yu Hong; Yin-Ling Liu; Jing-Ying Tan; Hao-Miao Liu; Gang-Liang Dai; Shi-Lu Chen; Ting Liu; Jin-Heng Li; Shi Tang
ORGANIC LETTERS, 2022

4. A Radical 1,4-Aryl Migration Enables Nickel-Catalysed Remote Cross-Electrophile Coupling of Β-Bromo Amino Acid Esters with Vinyl Triflates
Yin-Ling Liu; Jian Liu; Xin-Yu Li; Peng He; Yu-Xuan Liu; Mei Xiang; Shi Tang
Chemical Communications, 2024

5. Nickel-catalyzed Sequential 1,2-N-migration/bcbs Ring-Opening to Access Spirocyclobutyl Β-Amino Acid Esters.
Xin-Yu Li; Mei-Qiu Xiao; Li-Juan Zhou; Jia-Qi Zhang; Meng-Yan Zhao; Shuo-Wen Wang; Shi Tang
CHEMICAL COMMUNICATIONS, 2025

6. Asymmetric Synthesis of Β-Amino Acid Derivatives by Stereocontrolled C(sp3)-C(sp2) Cross-Electrophile Coupling Via Radical 1,2-Nitrogen Migration
Zicheng Liao; Zijun Li; Meiqiu Xiao; Youlin Deng; Zehan Ma; Lijuan Zhou; Gangliang Dai; Xinyu Li; Shuowen Wang; Shilu Chen; Jinheng Li; Shi Tang
NATURE COMMUNICATIONS, 2025