精细化工

新型富电子催化材料的设计、合成、表征与应用

1. Z. Zhang, K. Miyashita, T. Wu, J. Kujirai, K. Ogasawara, J. Li, M. Miyazaki, S. Satoru, M. Sasase, T. Tada*, H. Hosono*, M. Kitano*, Anion vacancies activate N2 to ammonia on Ba–Si orthosilicate oxynitride-hydride. Nature Chem., 2025, DOI: 10.1038/s41557-025-01737-8. （*通讯作者）

2. Z. Zhang*,Y. jiang, J. Li, M. Miyazaki, M. Kitano, H. Hosono, A 2D Ba2N Electride for Transition Metal-Free N2 Dissociation under Mild Conditions. J. Am. Chem. Soc., 2023, 145, 24482–24485 (Selected as Inside Cover).

3. Z. Zhang, T. Tsuchimochi, T. Ina, Y. Kumabe, S. Muto, K. Ohara, H. Yamada, S. L. Ten-no, T. Tachikawa*, Binary dopant segregation enables hematite-based heterostructures for highly efficient solar H2O2 synthesis. Nature Communications, 2022, 13, 1499 (Selected as Editors' Highlights).

4. Z. Zhang, H. Nagashima, T. Tachikawa*, Ultra-narrow depletion layers in hematite mesocrystal-based photoanode for boosting multihole water oxidation. Angew. Chem. Int. Ed., 2020, 59(23), 9047-9054 (Selected as hot paper and inside cover picture).

5. Z. Zhang, I. Karimata, H. Nagashima, S. Muto, K. Ohara, K. Sugimoto and T. Tachikawa*, Interfacial oxygen vacancies yielding long-lived holes in mesocrystalline hematite photoanodes. Nature Communications, 2019, 10, 4832.

6. Z. Zhang,# Y. Luo,# S. Liu, Q. Yao, S. Qing, Z-H. Lu*, PdAg-CeO2 nanocomposite anchored on mesoporous carbon: Highly efficient catalyst for hydrogen production from formic acid at room temperature, J. Mater. Chem. A, 2019, 7, 21438-21446.

7. Z. Zhang, X. Wei, Y. Yao, Z. Chen, A. Zhang, W. Li, W. D. Wu, Z. Wu,* X. Chen, D. Zhao. Conformal coating of Co/N‐doped carbon layers into mesoporous silica for highly efficient catalytic dehydrogenation–hydrogenation tandem reactions, Small, 2017, 13 (42), 1702243.

8. Z. Zhang, Z-H. Lu,* H. Tan, X. Chen, and Q. Yao. CeOx-modified RhNi nanoparticles grown on rGO as highly efficient catalysts for complete hydrogen generation from hydrazine borane and hydrazine, J. Mater. Chem. A, 2015, 3, 23520-23529.

9. Z. Zhang, Y. Wang, X. Chen, Z-H. Lu,* Facile synthesis of NiPt–CeO2 nanocomposite as an efficient catalyst for hydrogen generation from hydrazine borane, J. Power Sources, 2015, 291, 14-19.

10. Z. Zhang, Z-H. Lu,* and X Chen, Ultrafine Ni–Pt Alloy Nanoparticles Grown on Graphene as Highly Efficient Catalyst for Complete Hydrogen Generation from Hydrazine Borane, ACS Sustainable Chem. Eng., 2015, 3 (6), 1255-1261.