精细化工

有机合成化学、药物合成、精细化工等方面

Photoluminescence;Photocatalysis;Atomic Layer Deposition;Perovskite Solar Cells;Proton Irradiation;Science;Multidisciplinary;Humanities And Social Sciences;Chemical Vapor Deposition;Bivo4

[1] Wen-Yu Zhang, Qiu-Hua Xu, Qi Xue, Xia-Lu Cheng, Yu-Ting Cai, Jin-Heng Li, Yang Li*. Electrochemical Dehydrogenative [3+2]/[5+2] Annulation of N-arylacrylamides with γ,σ-Unsaturated Malonates via Direct C(sp3)–H/C(sp2)–H Functionalization. Org. Lett. 2024, 26, 6939−6943.
[2] Yu-Zhong Yang, Qi Xue, Zhi-Qiang Xiong, Yang Li*, Xuan-Hui Ouyang, Ming Hu*, Jin-Heng Li*. Divergent [2 + n] Heteroannulation of β‑CF3‑1,3-enynes with Alkyl Azides via Hydrogen Atom Transfer and Radical Substitution. Org. Lett. 2024, 26, 889−894.
[3] Yu-Zhong Yang, Gui-Fen Lv, Ming Hu, Yang Li*, Jin-Heng Li*. Nickel-Catalyzed Umpolung C-S Radical Reductive Cross Coupling of S-(trifluoromethyl)arylsulfonothioates with Alkyl Halides. Chin. Chem. Lett. 2023, 34, 108590.
[4] Qi Xue, Ren Wang, Wen-Yu Zhang, Fang-Fang Shen, Yang Li*, Qing Sun*, and Jin-Heng Li*. Pd-Catalyzed Intermolecular Carbonylative Dearomatization of Arylamines with Propargylic Acetates for Synthesis of Bridged Polycyclic Lactams. Org. Lett. 2023, 25, 4303-4307.
[5] Zhi-Jia Huang, Jin-Hao Qin, Miao-Lian Huang, Qing Sun, Hai-Yang Xie, Yang Li*, Jin-Heng Li*. Electrochemical Dehydrogenative Cyclization/Aromatization of Aniline-Tethered Alkylidenecyclopropanes: Facile Access to Benzo[c]carbazoles. Org. Chem. Front. 2023, 10, 1557-1563.
[6] Ya-Fei Han, Gui-Fen Lv, Yang Li*, Li-Jun Wu*, Xuan-Hui Ouyang, Jin-Heng Li*. The Transient-Chelating-Group-Controlled Stereoselective Rh(I)-Catalyzed Silylative Aminocarbonylation of 2-Alkynylanilines: Access to (Z)-3-(Silylmethylene)indolin-2-ones, Chem. Sci. 2022, 13, 9425-9431.
[7] Sheng-Yun Zhou, Ding Zhang, Xiao-Jie Liu, Jing-Hao Qin, Zheng-Li Fu, Shuang-Long Li, Fang-Jun Cai, Yang Li*, Jin-Heng Li*. Visible-Light-Driven Photoredox-Catalyzed C(sp3)-C(sp3) Cross-Coupling of N-arylamines with Cycloketone Oxime Esters, Org. Chem. Front. 2022, 9, 2534-2540.
[8] Mu-Jia Luo, Xuan-Hui Ouyang, Yan-Ping Zhu*, Yang Li*, Jin-Heng Li*. Metal-Free Electrochemical [3+2] Heteroannulation of Anilines with Pyridines Enabled by Dual C-H Radical Amination, Green Chem. 2021, 23, 9024-9029.
[9] Hui-Yuan Liu, Yuan Lu, Yang Li*, Jin-Heng Li*. Photocatalytic Decarboxylative [2+2+m] Cyclization of 1,7-Enynes Mediated by Tricyclohexylphosphine and Potassium Iodide, Org. Lett. 2020, 22, 8819-8823.
[10] Ming-Bo Zhou, Yang Li*, Xuan-Hui Ouyang, Jin-Heng Li*. Transformations of N-arylpropiolamides to Indoline-2,3-diones and Acids via C≡C Triple Bond Oxidative Cleavage and C(sp2)-H Functionalization, Sci. China Chem. 2020, 63, 222-227.

[1] 一种苯并氮杂卓类化合物的制备方法。李杨、潘高昂、李金恒，中国发明专利， 授权，2023-01-24，专利号：ZL 201911262667.8.
[2] 一种钯催化CO参与的1,4-烯炔芳构化反应合成芳胺基酚类化合物的方法。李杨、付政立、王仁、蔡芳俊、康星星，中国发明专利， 授权，2023-06-02，专利号：ZL 202210316109.0.
[3] 一种路易斯酸促进的烯烃和肟酯与胺的三组分反应方法。李杨、蔡芳俊、黄芷佳、付政立、余倩， 中国发明专利， 授权，2023-05-23，专利号：ZL 202210315862.8.
[4] 一种烯烃双官能化构建3-烷基吲哚类化合物的方法。李杨、李双龙、黄妙莲、侯高凯、张浩， 中国发明专利， 授权，2023-06-02，专利号：ZL 202210341012.5.
[5] 一种光氧化还原催化N-芳基胺与环酮肟酯C(sp3)-C(sp3) 交叉偶联方法。李杨、周生运、李金恒、张鼎， 中国发明专利， 授权，2023-09-08，专利号：ZL 202210155323.2.

1. 蓄光式可穿戴纽扣设计与产业化
立项时间: 2021-2021

2. 石墨烯/TMDs/BN范德华异质结构激发态双激子行为及其调制
立项时间: 2020-2022

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