新材料,石油炼制,石油化工,精细化工,生物医药

卟啉的合成，对手性分子的识别，金属蛋白和金属酶的化学仿生，卟啉相关的光电磁材料等。

Porphyrin;Crystal Structure;Circular Dichroism;Porphyrins;High-spin Transition Metal Complexes;Bisporphyrin;Coordination Polymer;Naphthyl;Chiral;Amino Acid Ester

1.Just a Proton: Distinguishing the Two Electronic States of Five-Coordinate High-Spin Iron(II) Porphyrinates with Imidazole/ate Coordination. C. J. Hu, C. D. Sulok, F. Paulat, N. Lehnert, A. I. Twigg, M. P. Hendrich, C. E. Schulz, and W. R. Scheidt. J. Am Chem. Soc.2010, 132, 3737.
2. Influence of Hydrogen Bonding on the Electronic Configuration of Five-Coordinate High-Spin Iron(II) Porphyrinates.  C. J. Hu, B. C. Noll, P. M. B. Piccoli, A. J. Schultz, C. E. Schulz, and W. R. Scheidt. J. Am Chem. Soc. 2008, 130, 3127.
3. Proton-Mediated Electron Configuration Change in High-Spin Iron(II) Porphyrinates. C. J. Hu, B. C. Noll, C. E. Schulz, and W. R. Scheidt, J. Am Chem. Soc. 2005, 127, 15018.
4.Electronic Configuration Assignment and the Importance of Low-Lying Excited States in High-Spin Imidazole-Ligated Iron(II) Porphyrinates. C. J. Hu, A. Roth, M. K. Ellison, J. An, C. E. Schulz, W. R. Scheidt.J. Am Chem. Soc. 2005, 127, 5675.
5. Enantioselectivity of a tartaric acid amide linked zinc bisporphyrinate towards amino acid esters. J. Wang, Z. H. Zhang, C. J. Hu*, Y. Wang. Dyes and Pigments, 2020, 108223. https://doi.org/10.1016/j.dyepig.2020.108223.
6. Precise control of chirality transfer by adjusting the alkyl substituents of guests.T. T. Hu, T. T. Liu, Z. Z. Zhang, Y. Wang, Y.G. Yang, D. J. Young, C. J. Hu*, J.-P. Lang*. Dyes and Pigments, 2019, 160, 692.
7. Stoichiometrically controlled chirality inversion in zinc bisporphyrinate–monoamine complexes. T. T. Hu, C. J. Hu*, Y. Wang, D. J. Young and J.-P. Lang*. Dalton Trans., 2018, 47, 5503.
8. Chirality Transfer from Chiral Monoamines to an m-Phthalic Diamide-Linked Zinc Bisporphyrinate with a Benzylamide Substituent. Q. Y. Hu, C. C. Zhuo, Y. Wang, C. J. Hu*, J.-P. Lang*. Inorg. Chem. 2017, 56 (17), 10204.
9. Crystallographic and Spectroscopic Studies of a Host-Guest Complex Consisting of a Novel Zinc Trisporphyrinate and a Chiral Monoamine. Z. Hn, L. Li, B. Shi, X. S. Fang, Y. Wang, C. J. Hu*.Inorg. Chem.2016, 55 (8), 3730.
10. m-Phthalic Diamide-Linked Zinc Bisporphyrinate: Spontaneous Resolution of Its Crystals and Its Application in Chiral Recognition of Amino Acid Esters. J. Jiang, X. S. Fang, B. Liu, and C. J. Hu*. Inorg. Chem., 2014, 53 (7), 3298.
11.  Chiral recognition of amino acid esters by a novel oxalic amide-linked bisporphyrin. J. Jiang, Z. Feng, B. Liu, C. J. Hu*, and Y. Wang,Dalton Trans., 2013, 42, 7651.
12. Facile One-pot Synthesis of Unprecedented ß, ß’-linked Porphyrin-Chlorin Heterodimers. X. X. Kai, J. X. Jiang, C. J. Hu*.Chem. Commun., 2012, 48 (36), 4302.

1. 血红素ci的仿生配合物的设计合成及性质功能的探索
立项时间: 2010-2012 项目经费：300000

2. 设计与合成新型双、多卟啉及其在手性识别中的应用
立项时间: 2013-2016 项目经费：800000

3. 手性双多卟啉的合成及其手性识别分离性能的研究
立项时间: 2020