精细化工

绿色有机合成、医药化工、精细化工

1、Accessing 3-Sulfonated vinylsilanes via Sulfonylation of α-Bromoallylsilane involving Photoinduced Radical Sulfur Dioxide Insertion，J. Org. Chem. 2025, DOI：10.1021/acs.joc.5c01237
2、EnT mediated alkoxy radical generation: the construction of 1,6-amino alcohols using bifunctional oxime esters, Chem. Commun. 2024, 60, 13766-13769
3、Photoinduced EnT-Mediated Sulfonamidylimination of Alkenes and (Hetero)arenes with Iminophenylacetic Acids Oxime Esters，Chem. Commun. 2024, 60, 7934-7937
4、Au(I)-Catalyzed Regioselective Hydrofluorination of Propargylamines Using Aqueous HF, J. Org. Chem. 2023, 88, 12074-12078
5、Gold catalyzed hydrofluorination of propargyl alcohols promoted by fluorine-hydrogen bonding， Chem. Commun. 2023, 59, 9078-9081
6、Iminyl-Radical-Mediated C-C Cleavage/Amination and Alkene Iminoamination Enabled by Visible-Light-Induced Cerium Catalysis, ACS Sustainable Chem. Eng. 2021, 9, 101-105.
7、Complementary Oxidative Generation of Iminyl-Radicals from α-Imino-oxy Acids: Silver Catalyzed C-H Cyanoalkylation of Heterocycles and Quinones, J. Org. Chem. 2020, 85, 2504-2511.
8、General 5-Halomethyl Isoxazolines Synthesis Enabled by Copper-Catalyzed Oxyhalogenation of Alkenes, J. Org. Chem. 2019, 84, 12656-12663.
9、TBHP-Induced Iodocyclization with I2: Atom Economic Synthesis of Iodinated Isoxazolines in Water under Mild Conditions, ACS Sustainable Chem. Eng. 2019, 7, 1875-1878.
10、Ligand-Accelerated Gold Catalyzed Addition of in Situ Generated Hydrazoic Acid to Alkynes under Neat Conditions, Org. Lett. 2017, 19, 3687-3690.

1、浙江省自然科学基金，LY21B020008, 配体氢键作用促进的金催化炔烃氢氟化反应研究, 2021/01-2023/12
2、浙江省自然科学基金，LY14B020005，以肼甲酸酯为前体的烷氧甲酰基自由基的温和引发及其反应研究，2014/01-2016/12
3、浙江省科技创新团队项目，2011R50017-10，负载纳米金属催化剂的NOx还原性能研究，2012/07-2015/06
4、国家自然科学基金青年项目，21102130，双环[3.2.0]庚酮类化合物的新反应研究，2012/01-2014/12
5、企业项目“核苷类药物关键中间体技术开发”
6、企业项目“杂环系列药物及其关键中间体技术开发”
7、企业项目“L-2-氨基丙醇的绿色合成新工艺研究”
8、企业项目“2,5-二甲氧基氯苯合成小试工艺研究”