精细化工

多金属氧簇﹑缩氨基硫脲衍生物等金属配合物及其纳米粒子的合成

Crystal Structure;Thiosemicarbazone;Cytotoxic Activity;Cytotoxicity;Hydrogen Bonding Interactions;Metal-organic Frameworks;Coordination Chemistry;Polyoxometalate;Hydrogen Bonding;Polyoxometalates

1)   C. L. Xing, J. N. Chang, M. Ma, P. T. Ma, L.Sun*, M. X. Li*, Ultrahigh-effificiency antibacterial and adsorption performance induced by copper-substituted polyoxomolybdate-decorated graphene oxide Nanocomposites， J. Colloid. Interface. Sci., 2022, 612, 664–678.IF=8.21, SCI一区
2)   J. Li, J. C. He, C. Si, M. X. Li*, Q. X. Han*, Z. L. Wang, J. W. Zhao, Special-selective C–H oxidation of toluene to benzaldehyde by a hybrid polyoxometalate photocatalyst including a rare [P6W48Fe6O180] 30– anion, J. Catal. 2020,392 , 244–253. IF=7.92, SCI一区，顶刊
3)   J. Li, J. C. Jiao, J. N. Chang, M. X. Li*, Q. X. Han*, Visible-light-driven C–N bonds formation by a nickle cluster substituted polyoxometalate-based photocatalyst, Inorg. Chem. 2021, 60，10022–10029. IF=5.165, SCI二区, Top
4)   Y. Fang, T. Y. Liu* , C. L. Xing, J. N. Chang, M. X. Li*, A blend hydrogel based on polyoxometalate for long-term and repeatedly localized antibacterial application study, Int. J. Pharmaceut., 2020, 591, 119990. IF= 5.875, SCI二区, Top,
5)   Y. Fang, C. L. Xing, J. Liu, Y. H. Zhang, M. X. Li*, Q. X. Han*, Supermolecular fifilm crosslinked by polyoxometalate and chitosan with superior antimicrobial effect, Int. J. Biol. Macromol. 2020, 154 , 732–738. IF=5.162，SCI二区
6)   Y. Fang, C. L. Xing, S. X. Zhan, M. Zhao, M. X. Li*, H. L. Liu*, Polyoxometalate-modified magnetic nanocomposite: a promising antibacterial material for water treatment, J. Mater. Chem. B, 2019, 7, 1933–1944. IF = 5.047，SCI 二区
7)   Y. Fang, C. L. Xing, S. X. Zhan, M. Zhao, M. X. Li*, H. L. Liu*, C. Z. Wang, A multifunctional magnetic-fluorescent nanoparticle: fabrication, bioimaging and potential antibacterial applications，ACS Biomater. Sci. Eng., 2019, 5, 12, 6779–6793. IF=4.511, SCI 二区
8)   C. L. Xing, P. T. Ma, M. Zhao, J. N. Chang, X. Y. Guo, L. Sun * , M. X. Li *, Facile and green synthesis of decatungstate-based nickel(II) complex coated onto modified Fe3O4 nanoparticles with enhanced antimicrobial activity against antibiotic-resistant bacteria†，CrystEngComm, 2021, 23, 3919–3928. SCI 二区
9)   Y. M. Ji; C. G. Ma; J. Li; H. Y. Zhao; Q. Q. Chen; M. X. Li* ; H. L. Liu* ; A magnetic adsorbent for the removal of cationic dyes from wastewater, Nanomaterials, 2018, 8, 710.
10)  J. Li, H. Y. Zhao, C. G. Ma, Q. X. Han, M. X. Li*, H. L. Liu, Preparation of Fe3O4@polyoxometalates, nanocomposites and their efficient adsorption of cationic dyes from aqueous solution, Nanomaterials, 2019, 9, 649. SCI 二区

(1) 李明雪，韩秋霞，方颜，邢翠丽，赵萌，多金属氧酸盐和壳聚糖交联的具有优异抗菌效果的超分子膜，授权公告日，2021年08月18日, 中国，专利号，ZL202010046825.2，
(2) 李明雪，方颜，邢翠丽，刘泰宇，王宇婷，多金属氧酸盐、掺杂其的共混水凝胶以及制备方法和在制备抗菌药物中的应用，授权公告日，2021年04月13日，中国，专利号，ZL202010863468.9.
(3) 李明雪，韩秋霞，李杰，方颜，司晨，多酸基金属有机框架材料及其合成方法和在光催化氧化苄胺偶联中的应用，授权公告日，2021年06月29日，中国，专利号，ZL202010856478.X.
(4) 李明雪，陈利娟，罗婕，赵俊伟，刘建彩，张芳，铜-铕异金属取代砷酸盐及其制备方法和应用，专利授权日：2016年4月27日，中国，专利号，ZL 2015 1 0035099. 3.

(1) 2016年国家自然科学基金面上资助项目: 缩氨基硫脲修饰的Strandberg型多钼氧簇有机-无机复合物的设计和生物活性评价（2671055），2017.1–2020.12，63万元
(2) 2010年国家自然科学基金面上资助项目：杂环缩氨基硫脲及其金属配合物的合成，晶体结构和生物活性（21071043）2011.01-2013.12。33万元

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