精细化工

1. 贵金属多酸催化剂
2. 多酸基分子笼、金属有机骨架材料
3. 多酸基抗肿瘤药物与抑菌制剂
4. 多酸基电/光催化剂、传感器

Polyoxometalates;Self-assembly;Palladium;Metal-organic Frameworks;Macroions;Vesicles;Post-functionalization;Supramolecular Chemistry;Polypalladates;Hydration Shell

1. K.-W. Tong†, Y.-H. Wang†, J. Du*, C.-Q. Chen, Y.-Q. Lan*, P. Yang*, Splicing Them Together: Construction of Polyoxovanadate–Organic Polyhedra-based Pyrgoscages and Catenanes. Angew. Chem. Int. Ed., 2025, e202504424.（中科院1区, TOP)
2. P. Yi, K.-W. Tong, C.-Q. Chen, Y. Zhang, J. Du*, P. Yang*, Switchable Iodine Adsorption Management in Polyoxovanadate-Cucurbit[6]uril-based Supramolecular Framework Materials. Chem. Mater., 2025, 37, 3542.
3. Y. Zhao†, Z. Liu†, Z. Qin, Q. Wen, J. Du, X.-Y. Ren, C.-Q. Chen, X. Peng*, U Kortz*, P. Yang*, Biomimetic Hierarchical Construction of Anti-Tumor Polyoxopalladates for Cancer Therapy. Angew. Chem. Int. Ed., 2025, 64, e202505564.（HOT Paper, 封面文章, 中科院1区, TOP)
4. L.-L. Liu, Z.-Y. Xu, P. Yi, C.-Q. Chen, Z.-L. Lang*, P. Yang*, Making an Inverted Keggin Ion Lacunary. Chem. Sci., 2024, 15, 16977.（HOT Paper, 中科院1区, TOP)
5. Y.-H. Wang, K.-W. Tong, S.-R. Xiong, C.-Q. Chen, Y.-H. Song*, P. Yang*, Steerable Structural Evolvement and Adsorption Behavior of Metastable Polyoxovanadate-Based Metal−Organic Polyhedra. Inorg. Chem., 2024, 63, 20984.（邀稿)
6. Y.-H. Wang†, K.-W. Tong†, C.-Q. Chen, J. Du, G.-P. Yang, P. Yang*, Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect. Inorg. Chem. Front., 2024, 11, 2726.（中科院1区)
7. H.-X. Sheng, B.-Y. Lin, C.-Q. Chen, J. Du, P. Yang*, From confined growth to enhanced peroxidase-like activity: Nucleation of a phosphate-mediated FeIII-CeIII-oxo cluster inside the {P8W48} nanoreactor. Polyoxometalates, 2024, 3, 9140060. （邀稿，封面文章)
8. Y. Zhao, C.-L. Li, C.-Q. Chen, J. Du, U. Kortz*, T. Gong*, P. Yang*, Last piece of the puzzle: lead-assisted assembly of an arsenopalladate nanostar as an antitumor metallodrug. Inorg. Chem. Front., 2024, 11, 1413. （HOT Paper, 中科院1区)
9. L.-L. Liu, L. Wang, X.-Y. Xiao, P. Yang*, J. Zhao*, U. Kortz*, Structural overview and evolution paths of lacunary polyoxometalates. Coord. Chem. Rev., 2024, 506, 215687. （中科院1区, TOP)
10. Y.-H. Wang†, K.-W. Tong†, C.-Q. Chen, J. Du*, P. Yang*, Weak Interaction-Steered Evolution of Polyoxovanadate-Based Metal-Organic Polyhedra from Transformation via Interlock to Packing. Chin. Chem. Lett., 2024, 35, 109066. （中科院1区, TOP)
11. Y. Zhao†, K. Li†, J. Du, C.-Q. Chen, S. Chen*, P. Yang*, Binary Heterogroup-Templated Scaffolds of Polyoxopalladates as Pre-Catalysts for Plasma-Assisted Ammonia Synthesis. ACS Appl. Mater. Interfaces, 2023, 15, 43899.
12. L.-L. Liu, Y.-H. Wang, X.-Y. Xiao, K.-W. Tong, Y. Zhao, C.-Q. Chen, J. Du*, P. Yang*, Engineering in Amino Acid-Functionalized Double-Layer Heteropolymolybdates: From Structural Control to Catalytic Activity. Rare Met., 2023, 42, 3345. （中科院1区)
13. Y. Niu, Y. Ding, H. Sheng, S. Sun, C. Chen, J. Du*, H.-Y. Zang*, P. Yang*, Space-Confined Nucleation of Semimetal-Oxo Clusters within a [H7P8W48O184]33− Macrocycle: Synthesis, Structure, and Enhanced Proton Conductivity. Inorg. Chem., 2022, 61, 21024.
14. P. Yang*, M. E. Mahmoud, Y. Xiang, Z. Lin, X. Ma, J. H. Christian, J. K. Bindra, J. S. Kinyon, Y. Zhao, C. Chen, T. Nisar, V. Wagner, N. S. Dalal, U. Kortz*, Host−Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n− (M = ScIII, CoII, CuII, L = AsO43−; M = CdII, HgII, L = PhAsO32−): Structure, Magnetism, and Catalytic Hydrogenation. Inorg. Chem., 2022, 61, 18524.
15. L. Liu, J. Jiang, G. Liu, X. Jia, J. Zhao*, L. Chen*, P. Yang*, Hexameric to Trimeric Lanthanide-Included Selenotungstates and Their 2D Honeycomb Organic−Inorganic Hybrid Films Used for Detecting Ochratoxin A. ACS Appl. Mater. Interfaces, 2021, 13, 35997.
16. P. Yang*, U. Kortz*, In Comprehensive Coordination Chemistry III; E. C. Constable, G. Parkin, L. Que Jr, Eds.; Elsevier: Amsterdam, 2021; Vol. 7, pp 4-28. (Book)
-------------------------------------------------------------------------------------------------------------------------------------
17. P. Yang, B. Alshankiti, N. M. Khashab*, Intrinsically Porous Molecular Building Blocks for Metal Organic Frameworks Tailored by the Bridging Effect of Counter Cations. CrystEngComm, 2020, 22, 2889. (邀稿)
18. P. Yang, W. Zhao, A. Shkurenko, Y. Belmabkhout, M. Eddaoudi, X. Dong, H. N. Alshareef, N. M. Khashab*, Polyoxometalate-Cyclodextrin Metal-Organic Frameworks: From Tunable Structure to Customized Storage Functionality. J. Am. Chem. Soc., 2019, 141, 1847. (封面文章)
19. P. Yang, T. Ma, Z. Lang, S. Misirlic-Dencic, A. M. Isakovic, A. Bényei, M. B. Čolović, I. Markovic, D. Z. Krstić, J. M. Poblet, Z. Lin*, U. Kortz*, Tetravalent Metal Ion Guests in Polyoxopalladate Chemistry: Synthesis and Anticancer Activity of [MO8Pd12(PO4)8]12− (M = SnIV, PbIV). Inorg. Chem., 2019, 58, 11294.
20. P. Yang, M. Alsufyani, A.-H. Emwas, C. Chen, N. M. Khashab*, Lewis Acid Guests in a {P8W48} Archetypal Polyoxotungstate Host: Enhanced Proton Conductivity via Metal-Oxo Cluster within Cluster Assemblies. Angew. Chem. Int. Ed., 2018, 57, 13046. (卷首插画)
21. P. Yang, U. Kortz*, Discovery and Evolution of Polyoxopalladates. Acc. Chem. Res., 2018, 51, 1599.
22. P. Yang, H. Li, T. Ma, F. Haso, T. Liu*, L. Fan, Z. Lin*, C. Hu, U. Kortz*, Rational Design of Organically Functionalized Polyoxopalladates and Their Supramolecular Properties. Chem. Eur. J., 2018, 24, 2466.
23. Z. Lang†, P. Yang†, Z. Lin, L. Yan, M.-X. Li, J. J. Carbó, U. Kortz*, J. M. Poblet*, Size and Charge Effect of Guest Cations in the Formation of Polyoxopalladates: a Theoretical and Experimental Study. Chem. Sci., 2017, 8, 7862.
24. P. Yang, Y. Xiang, Z. Lin, Z. Lang, P. Jiménez-Lozano, J. J. Carbó, J. M. Poblet*, L. Fan, C. Hu, U. Kortz*, Discrete Ag(I)-Pd(II)-Oxo Nanoclusters, {Ag4Pd13} and {Ag5Pd15}, and the Role of Metal–Metal Bonding Induced by Cation Confinement. Angew. Chem. Int. Ed., 2016, 55, 15766.
25. P. Yang, Z. Lin, B. S. Bassil, G. Alfaro-Espinoza, M. S. Ullrich, M.-X. Li, C. Silvestru, U. Kortz*, Tetra-Antimony(III)-Bridged 18-Tungsto-2-Arsenates(V), [(LSbIII)4(A-α-AsVW9O34)2]10– (L = Ph, OH): Turning Bioactivity On and Off by Ligand Substitution. Inorg. Chem., 2016, 55, 3718.
26. P. Yang, Z. Lin, G. Alfaro-Espinoza, M. S. Ullrich, C. Rat, C. Silvestru, U. Kortz*, 19-Tungstodiarsenate(III) Functionalized by Organoantimony(III) Groups: Tuning the Structure−Bioactivity Relationship. Inorg. Chem., 2016, 55, 251.
27. P. Yang, B. S. Bassil, Z. Lin, A. Haider, G. Alfaro-Espinoza, M. S. Ullrich, C. Silvestru, U. Kortz*, Organoantimony(III)-Containing Tungstoarsenates(III): From Controlled Assembly to Biological Activity. Chem. Eur. J., 2015, 21, 15600.
28. P. Yang†, Y. Xiang†, Z. Lin, B. S. Bassil, J. Cao, L. Fan, Y. Fan, M.-X. Li, P. Jiménez-Lozano, J. J. Carbó, J. M. Poblet, U. Kortz*, Alkaline Earth Guests in Polyoxopalladate Chemistry: From Nanocube to Nanostar via an Open-Shell Structure. Angew. Chem. Int. Ed., 2014, 53, 11974.

1. Polyoxometalates Comprising Noble Metals and Post-Transition Metals and Metal Clusters Thereof. T. Ma, U. Kortz, P. Yang, Z. Lin, W. W. Ayass. ExxonMobil Chemical Patents Inc., USA, 2022, 11241677.
2. Polyoxometalates Comprising Noble Metals and Carboxylate-Based Capping Groups and Metal Clusters Thereof. T. Ma, P. Yang, W. W. Ayass, Z. Lin, U. Kortz. ExxonMobil Chemical Patents Inc., USA, 2021, 11192835.
3. Polyoxometalates Comprising Noble Metals and Corresponding Metal Clusters. U. Kortz, Y. Xiang, Z. Lin, P. Yang, H. Jaensch, W. W. Ayass. ExxonMobil Chemical Patents Inc., USA, 2020, 10857527.
4. Preparation, Crystal Structure, Gas Adsorption and Catalytic Activity of Polyoxometalates Comprising Noble Metals and Corresponding Metal Clusters. U. Kortz, Y. Xiang, Z. Lin, P. Yang, H. Jaensch, W. W. Ayass. ExxonMobil Chemical Patents Inc., USA, 2017, WO 2017133898.

1. 湖南大学高层次人才启动基金，200万，2019年启动，主持
2. 国家自然科学基金青年项目，30万，2021年启动，主持
3. 湖南省自然科学基金青年项目，5万，2021年启动，主持
4. 长沙市自然科学基金重点项目，10万，2021年启动，主持
5. 湖南省教育厅科学研究基金优秀青年项目，6万，2022年启动，主持
6. 湖南省自然科学基金优秀青年项目，20万，2022年启动，主持
7. 湖南省“三尖”创新人才工程项目，40万，2022年启动，主持

技术咨询