天然气化工,新材料,石油炼制,石油化工,精细化工,生物医药

金属有机共轭体系的合成、性能及应用开发

聚碳硅烷;碳化硅;交联;超支化;过氧化苯甲酰;先驱体法;溶剂;分子量分布;烷氧化;分子量

Metallacycles;Osmium;Aromaticity;Density Functional Calculations;Metallapentalyne;Synthesis;Organometallic Chemistry;Cycloaddition;Ruthenium;Metallabenzene

发表学术论文近300篇， 50篇代表性论文：
1.Xu, B.; Chen, D.; Ruan, K.; Luo, M.; Cai, Y.; Qiu, J.; Zhou, W.; Cao, B.; Lin, Z.; Sessler, J. L.; Xia, H. Metal-centered planar [15]annulenes. Nature 2025, 641, 106-111.
2.Cui, F.; Gao, L.; Ruan, K.; Li, F.; Meng, M.; Ma, K.; Lu, Z.; Fei, J.; Tian, H.; Liu, L.; Lin, Y.; Xia, H. Fusion of Four Aromatic Rings via an Atom-Mutual-Embedding Strategy to Form a Tetrahexacyclic System. J. Am. Chem. Soc. 2025, 147, 13601-13609.
3.Yang, X.;  Zhang, X.; Cai, Y.; Xia, H.; Zhang, H. Metallaphosphirenes with σ-Aromaticity: Capture of Phosphorus Atom by Metalla-Aromatics. Angew. Chem. Int. Ed. 2025, DOI: 10.1002/anie.202512214.
4.Ruan, K.; Lu, Z.; Rao, R.; Liu, j. -j.; Chen, D.; Xia, H. Craig-Hückel Hybrid Aromatic Metalla-dehydro[11]annulenes Constructed by a Formal [10+1] Cycloaddition Reaction. Angew. Chem. Int. Ed. 2024, 63, e202316885. 
5.Yang, Y.; Chen, S.; Dai, Z.; Wei, H.; Wan, S.; Chen, Y.; Sun, J.; Liu, Z.; Ding, L.; Xia, H.; Chen, R.; Wang, H. Bridged Carbolong Modulating Interfacial Charge Transfer Enhancement for High-Performance Inverted Perovskite Solar Cells. Angew. Chem. Int. Ed. 2024, e202420262.
6.Xu, B.; Mao, W.; Lu, Z.; Cai, Y.; Chen, D.; Xia, H. Syntheses and reactivities of strained fused-ring metallaaromatics containing planar eleven-carbon chains. Nat. Commun. 2024, 154, 4378.
7.Zhuo, K.; Liu, Y.; Ruan, K.; Hua, Y.; Lin, Y.-M.; Xia, H. Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay. Nat. Synth. 2023, 28, e202201229.
8.Li, Q.; Hua, Y.; Tang, C.; Chen, D.; Luo, M.; Xia, H. Isolation, Reactivity, and Tunable Properties of a Strained Antiaromatic Osmacycle. J. Am. Chem. Soc. 2023, 145, 7580-7591.
9.Chen, L.; Lin, L.; Nath, A. R.; Zhu, Q.; Chen, Z.; Wu, J.; Wang, H.; Li, Q.; Lin, W.-F.; Zhu, J.; Xia, H. Synthesis and characterization of Craig-type antiaromatic species with [4n+2] π electrons. Proc. Natl. Acad. Sci. U. S. A. 2023, 120, e2215900120.
10.Luo, M.; Chen, D.; Li, Q.; Xia, H. Unique Properties and Emerging Applications of Carbolong Metallaaromatics. Acc. Chem. Res. 2023, 56, 924-937.
11.Tang, C.; Jiang, X.-L.; Chen, S.; Hong, W.; Li, J.; Xia, H. Stereoelectronic Modulation of a Single-Molecule Junction through a Tunable Metal-Carbon dπ‐pπ Hyperconjugation. J. Am. Chem. Soc. 2023, 145, 10404-10410.
12.Chen, S.; Feng, L.; Peng, L.; Gao, X.; Zhu, Y.; Yang, L.; Chen, D.; Zhang, K.; Guo, X.; Huang, F.; Xia, H. Synthesis and Optoelectronic Applications of dπ-pπ Conjugated Polymers with a Di-metallaaromatic Acceptor. Angew. Chem. Int. Ed. 2023, e202305489.
13.Hua,Y.; Luo, M.; Lu, Z.; Zhang, H.; Chen, D.; Xia, H. Experimental and theoretical evidences for the formation of transition metal complexes with five coplanar metal–carbon σ bonds. Natl. Sci. Rev. 2023, 12, nwad325.
14.Lai, X.; Chen, S.; Gu, X.; Lai, H.; Wang, Y.; Wang, H.; Qu, J.; Kyaw, A. K. K.; Xia, H.; He, F. Phenanthroline-Carbolong Interface Suppress Chemical Interactions with Active Layer Enabling Long-Time Stable Organic Solar Cells. Nat. Commun. 2023, 14, 3571.
15.Liu, H.-C.; Ruan, K.; Ma, K.; Fei, J.; Lin, Y.-M.; Xia, H. Synthesis of metalla-dual-azulenes with fluoride ion recognition properties. Nat. Commun. 2023, 14, 5583.
16.Tang, C.; Stuyver, T.; Lu, T.; Liu, J.; Ye, Y.; Gao, T.; Lin, L.; Zheng, J.; Liu, W.; Shi, J.; Shaik, S.; Xia, H.; Hong, W. Voltage-driven control of single-molecule keto-enol equilibrium in a two-terminal junction system. Nat. Commun. 2023, 14, 3657.
17.Cui, F.-H.; Li, Q.; Gao, L.-H.; Ruan, K.; Ma, K.; Chen, S.; Lu, Z.; Fei, J.; Lin, Y.-M.; Xia, H. Condensed Osmaquinolines with NIR-II Absorption Synthesized by Aryl C-H Annulation and Aromatization. Angew. Chem. Int. Ed. 2022, 134, e202211734. 
18.Chen, S.; Peng, L.; Liu, Y.; Gao, X.; Zhang, Y.; Tang, C.; Zhai, Z.; Yang, L.; Wu, W.; He, X.; Liu, L. L.; He, F.; Xia, H. Conjugated polymers based on metalla-aromatic building blocks. Proc. Natl. Acad. Sci. U. S. A. 2022, 119, e2203701119. 
19.Cui, F.-H.; Hua, Y.; Lin, Y.-M.; Fei, J.; Gao, L.-H.; Zhao, X.; Xia, H. Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal-Metallaaromatic Catalytic System. J. Am. Chem. Soc. 2022, 144, 5, 2301–2310. 
20.Lu, N.; Deng, Z.; Gao, J.; Liang, C.; Xia, H.; Zhang, P. An osmium-peroxo complex for photoactive therapy of hypoxic tumors. Nat. Commun. 2022, 13, 2245. 
21.Cai, Y.; Hua, Y.; Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.; Xia, H. Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118.
22.Tang, C.; Zhao, Y.; Wu, J.; Chen, Z.; Liu, L. L.; Tan, Y. Z.; Zhu, J.; Xia, H. Releasing Antiaromaticity in Metal-Bridgehead Naphthalene. J. Am. Chem. Soc. 2021, 143, 15587–15592.
23.Tang, C.; Huang, L.; Sangtarash, S.; Noori, M.; Sadeghi, H.; Xia, H.; Hong, W. Reversible Switching between Destructive and Constructive Quantum Interference Using Atomically Precise Chemical Gating of Single-Molecule Junctions. J. Am. Chem. Soc. 2021, 25, 9385-9392.
24. Liu, L.; Chen, S.; Qu, Y.; Gao, X.; Han, L.; Lin, Z.; Yang, L.; Wang, W.; Zheng, N.; Liang, Y.; Tan, Y.; Xia, H. He, F. Nanographene-Osmapentalyne Complexes as a Cathode Interlayer in Organic Solar Cells Enhance Efficiency over 18%. Adv. Mater. 2021, 32, 2101279.
25.Wang, J.; Li, J.; Zhou, Y.; Yu, C.; Hua, Y.; Yu, Y.; Li, R.; Lin, X.; Chen, R.; Wu, H.; Xia, H.; Wang, H. L. Tuning an Electrode Work Function Using Organometallic Complexes in Inverted Perovskite Solar Cells. J. Am. Chem. Soc. 2021, 143, 7759-7768.
26.Chen, D.; Hua, Y.; Xia, H. Metallaaromatic Chemistry: History and Development. Chem. Rev. 2020, 120, 12994-13086.
27.Tang, C.; Tang, Y.; Ye, Y.; Yan, Z.; Chen, Z.; Chen, L.; Zhang, L.; Liu, J.; Shi, J.; Xia, H.; Hong, W. Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature. Chem 2020, 6, 2770-2781
28.Chen, S.; Liu, L.; Gao, X.; Hua, Y.; Peng, L.; Zhang, Y.; Yang, L.; Tan, Y.; He, F.; Xia, H. Addition of Alkynes and Osmium Carbynes towards Functionalized dπ–pπ Conjugated Systems. Nat. Commun. 2020, 11, 4651.
29.Lu, Z.; Zhu, Q.; Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.; Xia, H. Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535. 
30.Luo, M.; Hua, Y.; Zhuo, K.; Long, L.; Lin, X.; Deng, Z.; Lin, Z.; Zhang, H.; Chen, D.; Xia, H. Carbolong Chemistry: Planar CCCCX-Type (X = N, O, S) Pentadentate Chelates by Formal [3+1] Cycloadditions of Metalla-Azirines with Terminal Alkynes. CCS Chemistry 2020, 2, 758-763.
31.Tang, C.; Chen, L.; Zhang, L.; Chen, Z.; Li, G.; Yan, Z.; Lin, L.; Liu, J.; Huang, L.; Ye, Y.; Hua, Y.; Shi, J.; Xia, H.; Hong, W. Multicenter-Bond-Based Quantum Interference in Charge Transport Through Single-Molecule Carborane Junctions. Angew. Chem. Int. Ed. 2019, 58, 10601-10605.
32.Zhu, C.; Xia, H. Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals. Acc. Chem. Res. 2018, 51, 1691-1700.
33.Zhuo, Q.; Zhang, H.; Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H. Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4, eaat0336.
34.Zhu, C.; Zhu, J.; Zhou, X.; Zhu, Q.; Yang, Y.; Wen, T. B.; Xia, H. Isolation of an Eleven - Atom Polydentate Carbon - Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem. Int. Ed. 2018, 57, 3154-3157.
35.Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang, H.; Xia, H. Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds. Nat. Commun. 2017, 8, 1912.
36.Li, R.; Lu, Z.; Cai, Y.; Jiang, F.; Tang, C.; Chen, Z.; Zheng, J.; Pi, J.; Zhang, R.; Liu, J.; Chen, Z.; Yang, Y.; Shi, J.; Hong, W.; Xia, H. Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions. J. Am. Chem. Soc. 2017, 139, 14344-14347.
37.Luo, M.; Long, L.; Zhang, H.; Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.; Xia, H. Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017, 139, 1822-1825.
38.Zhu, C.; Wu, J.; Li, S.; Yang, Y.; Zhu, J.; Lu, X.; Xia, H. Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-Membered Rings. Angew. Chem. Int. Ed. 2017, 56, 9067-9071.
39.Zhu, C.; Yang, C.; Wang, Y.; Lin, G.; Yang, Y.; Wang, X.; Zhu, J.; Chen, X.; Lu, X.; Liu, G ; Xia, H. CCCCC pentadentate chelates with planar Möbius aromaticity and unique properties. Sci. Adv. 2016, 2, e1601031.
40.Zhu, C.; Zhou, X.; Xing, H.; An, K.; Zhu, J.; Xia, H. σ-Aromaticity in an Unsaturated Ring: Osmapentalene Derivatives Containing a Metallacyclopropene Unit. Angew. Chem. Int. Ed. 2015, 54, 3102-3106.
41.Zhu, C.; Yang, Y.; Wu, J.; Luo, M.; Fan, J.; Zhu, J.; Xia, H. Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynes by the Reactions of Osmapentalene with Allene, Alkyne, and Alkene. Angew. Chem. Int. Ed. 2015, 54, 7189-7192.
42.Zhu, C.; Yang, Y.; Luo, M.; Yang, C.; Wu, J.; Chen, L.; Liu, G.; Wen, T.; Zhu, J.; Xia, H. Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics. Angew. Chem. Int. Ed. 2015, 54, 6181-6185.
43.Xu, H.; Pang, X.; He, Y.; He, M.; Jung, J.; Xia, H.;Lin, Z. An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic–Inorganic Nanocomposites. Angew. Chem. Int. Ed. 2015, 54, 4636-4640.
44.Zhu, C.; Luo, M.; Zhu, Q.; Zhu, J.＊; Schleyer, P. v. R.; Wu, J. I. C.; Lu, X.; Xia, H. Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums. Nat. Commun. 2014, 5, 3265.
45.Cao, X.-Y.; Zhao, Q.; Lin, Z.; Xia, H. The Chemistry of Aromatic Osmacycles. Acc. Chem. Res.2014, 47, 341-354.
46.Zhu, C.; Zhu, Q.; Fan, J.; Zhu, J.; He, X.; Cao, X.-Y.; Xia, H. A Metal-Bridged Tricyclic Aromatic System: Synthesis of Osmium Polycyclic Aromatic Complexes. Angew. Chem. Int. Ed. 2014, 53, 6232-6236.
47.Wang, T.; Zhu, J.; Han, F.; Zhou, C.; Chen, H.; Zhang, H.; Xia, H. Synthesis of Five-Membered Osmacycloallenes and Conversion into Six-Membered Osmacycloallenes. Angew. Chem. Int. Ed. 2013, 52, 13361-13364.
48.Wang, T.; Zhang, H.; Han, F.; Long, L.; Lin, Z.; Xia, H. Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization in an Osmabenzene System. Angew. Chem. Int. Ed. 2013, 52, 9251-9255.
49.Niu, Y.; Han, F.; Zhang, Q.; Xie, T.; Lu, L.; Li, S.; Xia, H. Off/On Fluorescent Chemosensors for Organotin Halides Based on Binuclear Ruthenium Complexes. Angew. Chem. Int. Ed. 2013, 52, 5599-5603.
50.Zhu, C.; Li, S.; Luo, M.; Zhou, X.; Niu, Y.; Lin, M.; Zhu, J.; Cao, Z.; Lu, X.; Wen, T.; Xie, Z.; Schleyer, P. v. R.; Xia, H. Stabilization of anti-aromatic and strained five-membered rings with a transition metal. Nat. Chem. 2013, 5, 698-703.

1. 唯金属中心手性锇杂戊搭烯并氧杂三元环配合物及其制备方法与应用
南方科技大学
夏海平; 陈大发; 路正宇; 罗明; 廖永杰; 杨磊
公开日期: 2023-08-04 申请日期: 2023-05-05 公开号: CN116535444A

2. 一种CNC型三齿钌配合物及其制备方法与应用
南方科技大学
郑雪娟; 陈大发; 罗明; 路正宇; 夏海平
公开日期: 2023-06-06 申请日期: 2023-01-10 公开号: CN116217625A

3. 一种含环内锇亚乙烯键金属杂环化合物及其合成方法与应用
南方科技大学
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4. 一种可光催化苄胺氧化偶联制备亚胺的CCC型三齿铱配合物
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5. 2-取代铑杂碳龙配合物及其合成方法
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6. 2-取代金属铱杂碳龙配合物的一步合成法
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7. 一种含锇共轭聚合物及其制备方法与应用
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8. 一种含锇共轭聚合物及其制备方法与应用
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XIA HAIPING; CHEN SHIYAN; ZHANG YING; ZHU YONGFA; ZHUO QINGDE; YANG LIULIN; HE XUMIN
公开日期: 2021-05-04 申请日期: 2020-01-16 公开号: CN112745485A

9. 一种含锇共轭聚合物及其制备方法与应用
UNIV XIAMEN
XIA HAIPING; CHEN SHIYAN; ZHANG YING; ZHU YONGFA; ZHUO QINGDE; YANG LIULIN; HE XUMIN
公开日期: 2021-05-04 申请日期: 2020-01-16 公开号: CN112745485A

10. Chain multiyne compound, preparation method and application thereof
Xiamen University
Haiping Xia; Qingde Zhuo; Jianfeng Lin; Xiaoxi Zhou; Zhixin Chen; Yifan Shao; Hong Zhang; Xumin He
公开日期: 2019-05-14 申请日期: 2017-11-13 公开号: US10287225B2

11. 锇过氧配合物及其制备方法和应用
厦门大学
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12. CHAIN MULTIYNE COMPOUND, PREPARATION METHOD AND APPLICATION THEREOF
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公开日期: 2018-03-08 申请日期: 2017-11-13 公开号: US2018065908A1

13. 一种抗菌纳滤膜的制备方法及其应用
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公开日期: 2017-06-13 申请日期: 2017-01-25 公开号: CN106823833A

14. 金属桥位稠环化合物及其制备方法和用途
厦门大学
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15. 链状多炔化合物及其制备方法和应用
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公开日期: 2017-01-04 申请日期: 2015-05-13 公开号: CN106279100A

16. 链状多炔化合物及其制备方法和应用
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公开日期: 2017-01-04 申请日期: 2015-05-13 公开号: CN106279100A

17. 锇杂稠环化合物及其制备方法、含有该化合物的组合物以及应用
厦门大学
夏海平; 朱从青; 刘刚; 杨宇惠; 何旭敏
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18. 一种金属桥位稠环化合物及其中间体和制备方法及应用
UNIV XIAMEN
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19. 锇杂稠环化合物及其制备方法、含有该化合物的组合物以及应用
UNIV XIAMEN
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20. 一种多功能两亲性三元共聚物及其制备方法和应用
厦门大学; 厦门世达膜科技有限公司
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公开日期: 2016-05-18 申请日期: 2016-02-18 公开号: CN105585659A

主持的主要科研项目（其中三项国家基金委“重点项目”在研）：
1.2026.01-2030.12，国家自然科学基金重点项目，碳龙配合物的芳香性骨架编辑；
2.2024.01-2026.12，国家自然科学基金原创探索项目，基于金属-碳键形成的主链重构——非共轭聚多炔链螯合金属法构筑d轨道参与π共轭的高分子22350009，300万；
3.2022.01-2025.12，国家自然科学基金重大研究计划-重点项目，唯金属中心手性碳龙配合物的制备及其催化性能研究92156021，370万；
4.2020.01-2024.12，国家自然科学基金重点项目（前沿导向），碳龙化学：结构基元创新、性能与应用研究21931002，300万；
5.2020.11-2023.10，深圳市科技创新委员会基础研究-重点项目，基2020N052金属参与的π共轭体系光能转化材料应用研究JCYJ20200109140812302，200万；
6.2020.01-2023.12，广东省科技厅，广东省催化化学重点实验室2020B121201002，300万；
7.2018.01-2021.12，国家基金联合基金项目，金属杂芳香体系-光能转化材料新基元的设计合成、性能调控及应用基础U1705254，204万；
8.2016.01-2019.12，国家基金国际（地区）合作项目，含主族杂原子锇/铱杂稠环的设计、合成与应用2151101071，99.92万；
9.2015.01-2019.12，国家自然科学基金重大项目，基于三键化学的高分子合成，课题四“基于三键的聚合物新功能和应用”21490573，523.5万；
10.2010.1-2013.12，国家杰出青年科学基金，金属杂芳香化合物的合成方法学，性能与应用研究20925208，200万；

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