精细化工

过渡金属催化，自由基化学

25.Bin Liu, Andrew M. Romine, Camille Z. Rubel, Keary M. Engle, and Bing-Feng Shi Chelation-Assisted, Transition-Metal-Catalyzed Functionalization of Inert C(sp3)–H Bonds. Chem. Rev. 2021. 121, 14957–15074.
24.Liu, B.; Elder, W. Z.; Miyake, G. M. Scalable and Phosphine-Free Conversion of Alcohols to Carbon–Heteroatom Bonds through the Blue Light-Promoted Iodination Reaction. J. Org. Chem. 2020. 85, 3717–3727. (One of the most read articles, March 2020)
23.Liu, B.; Alegre-Requena, J.; Paton, R.; Miyake, G. M. Unconventional Reactivity of Ethynylbenziodoxolone (EBX) Reagents and Thiols: Scope and Mechanism. Chem. Eur. J. 2020, 26, 2386 –2394. (Inside Cover, hot paper)
22.Liu, B.; Lim, C.-H.; Miyake, G. M. Light driven intermolecular charge transfer induced reactivity of ethynylbenziodoxol(on)e (EBX) and phenols. J. Am. Chem. Soc. 2018, 140, 12829−12835.
21.Lim, C.-H.; Kudisch, M.; Liu, B.; Miyake, G. M. C–N Cross-Coupling via Photoexcitation of Nickel–Amine Complexes. J. Am. Chem. Soc. 2018, 140, 7667–7673.
20.Liu, B.; Lim, C.-H.; Miyake, G. M. Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer. Synlett 2018, 29, 2449−2455.
19.Liu, B.; Lim, C.-H.; Miyake, G. M. Visible Light-Promoted C-S Cross-Coupling via Intermolecular Charge-Transfer. J. Am. Chem. Soc. 2017, 139, 13616–13619. (1 most read article, October 2017, highlighted in SYNFACTS)
18.Liu, B.; Zhang, Z.-Z.; Li, X.; Shi, B.-F. Nickel(II)-Catalyzed Direct Arylation of Aryl C–H Bonds with Aryl-boron Reagents Directed by a Removable Bidentate Auxiliary. Org. Chem. Front. 2016, 3, 897−900.
17.Liu, B.; Shi, B.-F. γ-Lactone Synthesis via Palladium(II)-Catalyzed Lactonization of Unactivated Methylene C(sp3)–H Bonds. Synlett 2016, 27, 2396–2400.
16.Zhang, Z.-Z.; Liu, B.; Xu, J.-W.; Yan, S.-Y.; Shi, B.-F. Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes. Org. Lett. 2016, 18, 1776−1779.
15.Zhao, S.; Liu, B.; Zhan, B.-B.; Zhang, W.-D.; Shi, B.-F. Nickel-Catalyzed Ortho-Arylation of Unactivated (Hetero)aryl C–H Bonds with Arylsilanes Using a Removable Auxiliary. Org. Lett. 2016, 18, 4586−4589.
14.Liu, B; Shi, B.-F. Transition-Metal-Catalyzed Etherification of Unactivated C-H Bonds. Tetrahedron Lett. 2015, 56, 15−22.
13.Liu, B.; Hu, F.; Shi, B.-F. Recent Advances on Ester Synthesis via Transition-Metal-Catalyzed C-H Activation. ACS Catalysis 2015, 5, 1863−1881.
12.Yan, S.-Y.;‡ Liu, Y.-J.;‡ Liu, B.; Liu, Y-H.; Shi, B.-F. Nickel-Catalyzed Thiolation of Unactivated Aryl C–H Bonds: An Efficient Access to Diverse Aryl Sulfides. Chem. Commun. 2015, 51, 4069–4072.
11.Li, B.; Liu, B.; Shi, B.-F. Copper-Catalyzed ortho-Halogenation of Arenes and Heteroarenes Directed by a Removable Auxiliary. Chem. Commun. 2015, 51, 5093–5096.
10.Yan S.-Y.;‡ Liu Y.-J.;‡ Liu B.; Liu Y-H.; Zhang Z-Z.; Shi, B.-F. Nickel-Catalyzed Direct Thiolation of Unactivated C(sp3)-H Bonds with Disulfides. Chem. Commun. 2015, 51, 7341–7344.
9.Zhan, B.-B.; Liu, B.; Shi, B.-F. Recent Progress on Nickel-Catalyzed Direct Functionalization of Unactivated C-H Bonds (in Chinese). Chin. Sci. Bull. 2015, 60, 1–11.
8.Zhang, Z.-Z.; Liu, B.; Wang, C-Y.; Shi, B.-F. Cobalt(III)-Catalyzed C2-Selective C-H Alkynylation of Indoles. Org. Lett. 2015, 17, 4094–4097.
7.Zhao, S.; Chen, F-J.; Liu, B.; Shi, B.-F. Copper-Catalyzed Direct Acyloxylation of C(sp2)-H Bonds with Benzoic Acids. SCIENCE CHINA Chemistry, 2015, 58, 1302–1309.
6.Li, B.; Wang, S-Q.; Liu, B.; Shi, B.-F. Synthesis of Oxazolines from Amides via Palladium-Catalyzed Functionalization of Unactivated C(sp3)-H Bond. Org. Lett. 2015, 17, 1200–1203.
5.Liu, B.; Jiang, H.-Z.; Shi, B.-F. Palladium-Catalyzed Oxidative Olefination of Phenols Bearing Removable Directing Groups under Molecular Oxygen. J. Org. Chem. 2014, 79, 1521–1526.
4.Liu, B.; Jiang, H.-Z.; Shi, B.-F. Palladium-Catalyzed Oxidative Alkoxy- carbonylation of 2-Phenoxypyridine Derivatives with CO and Alcohols. Org. Biomol. Chem. 2014, 12, 2538–2542.
3.Liu, B.; Hu, F.; Shi, B.-F. Synthesis of Sterically Congested Polycyclic Aromatic Hydrocarbons: Rh(III)-Catalyzed Cascade Oxidative Annulation of Aryl Ketoximes with Internal Alkynes by Sequential Cleavage of Multiple C-H Bonds. Adv. Synth. Catal. 2014, 356, 2688–2696.
2.Zhang, B.; Guan, H.-X.; Liu, B.; Shi, B.-F. Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)-H Bonds Assisted by Bidentate Directing Groups. Chin. J. Org. Chem. 2014, 34, 1487–1498.
1.Liu, B.; Shi, B.-F. Efficient Synthesis of Carboxylic Esters via Pd(II)-Catalyzed Direct Alkoxycarbonylation of Arenes with CO and Alcohols. Synlett 2013, 24, 2274–2278.

1.Miyake, G. M.; Liu, B.; Lim, C.-H. Photocatalyst-free, light-induced carbon-sulfur cross-coupling methods. US20180370911A1.
2.Miyake, G. M.; Lim, C.-H.; Kudisch, M.; Liu, B. Methods for forming aryl carbon-nitrogen bonds using light and photoreactors useful for conducting such reactions. US20190345122A1.

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