专家介绍:
田永辉,教授,博士生导师。本科毕业于北京化工大学高分子材料专业,硕士毕业于浙江大学材料学专业。2011年于Georgetown University获化学博士学位,随后三年于Los Alamos National Laboratory从事博士后研究,2014年四川大学生命科学学院任特聘研究员,2018入职于西北大学化学与材料科学学院。目前研究工作主要通过以下几个方面,实现氮气、二氧化碳等惰性小分子的活化和化学键的催化转变,理解以多电子转移为特征的能源小分子转化机制:等离子体化学与氧化还原反应过程的质谱原位探测;纳米尺度化学反应环境的构建及其能源小分子的活化与转化;低纬材料结构与性能的理论计算。
https://faculty.nwu.edu.cn/YonghuiTian/zh_CN/index/57173/list/
代表性论文
Wen Liu, Yonghui Tian, Observing C–N bond formation in plasma: a case study of benzene and dinitrogen coupling via an arylnitrenium ion intermediate, Phys. Chem. Chem. Phys., 2024, https://doi.org/10.1039/D4CP01594K
Yue Tang, Jianxiong Dai, Pei Zhang, Guanghui Niu, Yixiang Duan, Yong-Hui Tian, Selective Nitrate Synthesis by Plasma/Liquid Water Reaction: An Enhanced Oxidative Strength Mechanism in Nitrogen Discharge, ACS Sustainable Chem. Eng., 2024, https://doi.org/10.1021/acssuschemeng.4c03296
Xia Xu,Xuyang Zhao,Jie Tang,Yixiang Duan*,Yong-Hui Tian*, Direct Amination of Benzene with Molecular Nitrogen Enabled by Plasma-Liquid Interactions, Angew. Chem. Int. Ed., 2022, https://doi.org/10.1002/anie.202203680.
Xia Xu, Jianxiong Dai, Xing Guo, Cheng Qian, Pei Zhang, Yixiang Duan *, Yonghui Tian*, Effective N2 capture by aryl cations at ambient temperature and pressure, Phys. Chem. Chem. Phys., 2021, 23, 10763–10767 (DOI: 10.1039/d1cp00903f).
Zhijun Huang, Naizhi Yao, Xiaoting Li, Yonghui Tian*, Yixiang Duan*, Self-extending DNA-Mediated Isothermal Amplification System and Its Biosensing Applications, Anal. Chem., 2021, 93, 14334–14342 (DOI: 10.1021/acs.analchem.1c03636).
Yong-Hui Tian,* Shuangli Hu, Xiaolan Sheng, Yixiang Duan, Jacek Jakowski, Bobby G. Sumpter, Jingsong Huang, Non-Transition-Metal Catalytic System for N2 Reduction to NH3: A Density Functional Theory Study of Al-Doped Graphene, J. Phys. Chem. Lett., 2018, 9, 570−576 (DOI: 10.1021/acs.jpclett.7b03094).
Yong-Hui Tian,* Jingsong Huang, Xiaolan Sheng, Bobby G. Sumpter, Mina Yoon, Miklos Kertesz, Nitrogen Doping Enables Covalent-Like π−π Bonding between Graphenes, Nano Lett., 2015, 15, 5482−5491 (https://doi.org/10.1021/acs.nanolett.5b01940).
Yong-Hui Tian*, Bobby G. Sumpter, Shiyu Du, Jingsong Huang*, Pancake π–π Bonding Goes Double: Unexpected 4e/All-Sites Bonding in Boron- and Nitrogen-Doped Phenalenyls, J. Phys. Chem. Lett., 2015, 7, 2318–2325 (https://doi.org/10.1021/acs.jpclett.5b00857).
Chenyu Li , Xi Tang , Liuqing Zhang , Cuihong Li , Zhengping Liu , Zhishan Bo , Yong Qiang Dong ,* Yong-Hui Tian ,* Yuping Dong , Ben Zhong Tang*, Reversible Luminescence Switching of an Organic Solid: Controllable On–Off Persistent Room Temperature Phosphorescence and Stimulated Multiple Fluorescence Conversion, Adv. Optical Mater. 2015, DOI: 10.1002/adom.201500115.
Yong-Hui Tian, Aaron W. Pierpont, Enrique R. Batista*, How Does Nishibayashi’s Molybdenum Complex Catalyze Dinitrogen Reduction to Ammonia?, Inorg. Chem., 2014, 53, 4177−4183 (dx.doi.org/10.1021/ic500221n).