精细化工

绿色催化反应过程与工艺：1、从源头上解决化工过程安全的催化反应技术与工艺；2、化工过程强化及工程放大技术。

[1] Hefang Wang,Luming Wu,Aizhong Jia,Xiaona Li,Zetao Shi,Mengmeng Duan,Yanji Wang. Ni nanoparticles encapsulated in the channel of titanate nanotubes:Efficient noble-metal-free catalysts for selective hydrogen generation from hydrous hydrazine[J].Chemical Engineering Journal, 2018, 332: 637-646
[2] Aina Yang,Tong Wang,Zhihui Li,Yuanyuan Xu,Liya Gao,Dongsheng Zhang,Shufang Wang,Xinqiang Zhao,Yanji Wang.One-step synthesis of cyclohexylamine from   benzene, hydroxylamine and hydrogen over vanadium and ruthenium catalysts[J].Research on Chemical Intermediates, 2018, 44: 339-354
[3] Zhihui Li, Xudong Qi, Liya Gao, Yuanyuan Xu, Dongsheng Zhang, Shufang Wang, Xinqiang Zhao, Yanji Wang.Application of hydroxylamine ionic liquid salts in hydroxylation of benzene to phenol with ammonium molybdate-copper chloride-ionic liquid system[J].Chemistry Letters, 2017, 46(3): 289-292
[4] Fang Li,Xi Wang,Hongqin Li,Shufang Wang,Wei Xue,Yanji Wang.The induction period and novel active species in Zn(OAc)2 catalyzed synthesis of aromatic carbamates [J].Catalysis Letters, 2017, 147: 1478-1484
[5] Fang Li,Xi Wang,Hongqin Li,Wei Xue,Yanji Wang,Xinqiang Zhao.Facile and green preparation of zinc oxyacetate [J].Chemistry Letters, 2017, 46, 1151-1154
[6] Hefang Wang, Cunyue Wang, Yongfang Yang, Meng Zhao, Yanji Wang. H3PW12O40/mpg-C3N4   as an efficient and reusable bifunctional catalyst in one-pot   oxidation-Knoevenagel condensation tandem reaction [J]. Catalysis Science   Technology, 2017, 7: 405-417
[7] Hefang Wang, Meng Zhao, Qian Zhao, Yongfang Yang, Cunyue Wang, Yanji Wang. In-Situ immobilization of H5PMo10V2O40 on protonated graphitic carbon nitride under hydrothermal conditions: A highly efficient and reusable catalyst for hydroxylation of benzene [J]. Industrial & Engineering Chemistry Research, 2017, 56: 2711-2721
[8] Zhihui Li，Qiusheng Yang，Liya Gao，Yuanyuan Xu，Dongsheng Zhang，Shufang Wang，Xinqiang Zhao，Yanji Wang. Reactivity of hydroxylamine ionic liquid salts in the direct synthesis of caprolactam from cyclohexanone under mild conditions [J].RSC Advances，2016, 29: 83619-83625
[9] Yuanyuan Xu，Qiusheng Yang，Zhihui Li，Liya Gao，Dongsheng Zhang，Shufang Wang，Xinqiang Zhao，Yanji Wang.Ammoximation of cyclohexanone to cyclohexanone oxime using ammonium   chloride as nitrogen source ammonium chloride as nitrogen source [J]. Chemical Engineering Science, 2016, 152：717-723
[10] Guirong Wang，Dan Ma，Xiaoqiang Jia，Xuexia Cui，Xinqiang Zhao，Yanji Wang.In situ preparation of nanometer-scale zinc oxide from zinc acetate in the reaction for the synthesis of dimethyl toluene dicarbamate and its catalytic decomposition performance [J].Industrial & Engineering Chemistry Research, 2016, 55: 8011-8017
[11] Hefang Wang，Luping Fang，Yongfang Yang，Rongbin Hu，Yanji Wang.Immobilization Na7PW11O39 on quanternary ammoniumfunctionalized chloromethylated polystyrene by electrostaticinteractions:An efficient recyclable catalyst for alcohol oxidation[J].Applied Catalysis A: General, 2016, 520: 35-43
[12] Fang Yang, Wei Xue,Dongsheng Zhang,Fang Li,Yanji Wang.Hydrolysis of cyclohexyl acetate to cyclohexanol with high selectivity over SO3H-functionalized ionic liquids[J].Reaction Kinetics, Mechanisms and Catalysis,2016,117(1):329-339
[13] Zhihui Li, Qiusheng Yang,Xudong Qi,Yuanyuan Xu,Dongsheng Zhang,Yanji Wang,Xinqiang Zhao.A novel hydroxylamine ionic liquid salt resulting from the stabilization of NH2OH by a SO3H-functionalized ionic liquid [J].Chemical Communications, 2015, 51(10): 1930-1932
[14] Yuanyuan Xu,Zhihui Li,Liya Gao,Dongsheng Zhang,Xinqiang Zhao,Shufang Wang,Yanji Wang.An integrated process for the synthesis of solid hydroxylamine salt with ammonia and hydrogen peroxide as raw materials[J].Industrial & Engineering Chemistry Research,2015,54 (3):1068-1073
[15] Fang Li, Huanhuan Xu,Wei Xue,Yanji Wang,Xinqiang Zhao.The one-pot synthesis of methylene diphenyl-4,4-dicarbamate[J]. Chemical Engineering Science, 2015,135:217-222
[16] Shujuan Sun,Dongsheng Zhang,Chunyu Li,Yanji Wang.DFT study on the adsorption and dissociation of H2S on CuO(111) surface[J].RSC Advances, 2015, 5: 21806-21811.
[17] Shujuan Sun,Chunyu Li,Dongsheng Zhang,Yanji Wang.Density functional theory study of the adsorption and dissociation of O2 on CuO(111) surface[J].Applied Surface Science, 2015, 333: 229-234
[18] Jing Li,Lihong Yang,Fang Li,Wei Xue,Yanji Wang.Hydration of cyclohexene to cyclohexanol over SO3H-functionalized imidazole ionic liquids[J].Reaction Kinetics Mechanisms Catalysis,2015,114:173-183
[19] Xiaoshu Ding,Hao Liu,Naihua Li,Shufang Wang,Guirong Wang,Xinqiang Zhao,Yanji Wang.Isobaric vapor-liquid equilibria for the binary and ternary systems of methanol, epichlorohydrin, and glycerol dimethyl ether at 101.3kPa[J]. Journal of Chemical and Engineering Data, 2015, 60(3): 541-544
[20] Qiusheng Yang,Haiou Wang,Xiaoshu Ding,Xue Yang,Yanji Wang.One-pot synthesis of dimethyl carbonate from carbon dioxide, cyclohexene oxide, and methanol[J].

[1] 王延吉，杨爱娜，张东升，李志会，徐元媛，王淑芳，赵新强. 由苯一锅法制备环己胺的方法，中国发明专利，ZL201610647696.6，2018年3月授权。
[2] 王延吉，徐元媛，张东升，李志会，孔令凯，王淑芳，赵新强. 一种分解氯化铵同时制备有机碱盐酸盐和环己酮肟的方法，中国发明专利，ZL201510995088.X，2017年8月授权。
[3] 王延吉，王淑芳，孙蕾，王玲，张东升，赵新强. 一种硝基苯加氢合成苯胺的工艺，中国发明专利，ZL201410526666.0，2016年1月授权。
[4] 王延吉，李志会，齐旭东，张东升，徐元媛，杨秋生，赵新强. 一种以环己酮为原料直接合成己内酰胺的方法，中国发明专利，ZL201410347005.1，2016年7月授权。
[5] 王延吉，李志会，张东升，齐旭东，徐元媛，杨秋生，赵新强. 一种由环己酮和离子液体型羟胺盐一步合成己内酰胺的方法，中国发明专利，ZL201410347004.7，2016年3月授权。
[6] 王延吉，孙蕾，王淑芳，张东升，赵新强.一种具有高活性催化性能的反应构件，中国发明专利，ZL201410526689.1，2016年8月授权。
[7] 王延吉，张东升，徐元媛，金常青，张广林，薛伟，王淑芳，赵新强.一种合成羟胺盐的方法，中国发明专利，ZL201310351567，2015年5月授权。
[8] 王延吉，王桂荣，贾晓强，赵新强.利用甲苯二胺和碳酸二甲酯制备甲苯二异氰酸酯的工艺，中国发明专利，ZL201410148796，2015年6月授权。
[9] 王延吉，李志会，张东升，徐元媛，金长青，王淑芳，赵新强. 一种离子液体型羟胺盐的制备方法，中国发明专利，ZL201310481404，2015年8月授权。
[10] 王延吉，徐元媛，张东升，李志会，金长青，高丽雅，王淑芳，赵新强.一种低附加值氯化铵的资源利用方法，中国发明专利，ZL201410008305，2015年8月授权。
[11] 王延吉，张东升，徐元媛，檀学军，张广林，陈英曼，高丽雅，赵新强.一种在酸性离子液中催化环己酮肟水解反应的方法，中国发明专利，ZL201310043287，2015年8月授权。
[12] 王延吉，赵茜，王淑芳，杨云芳，任小亮，赵新强.一种由硝基苯加氢直接合成环己酮的方法，中国发明专利，ZL201410243651，2015年11月授权。

1.国家自然科学基金重点项目（21236001）：“清洁生产异氰酸酯安全反应过程构建及关键基础问题研究”，2013.01-2017.12，300万元，负责人。
2.高等学校博士学科点专项科研基金（博导类）：“合成MDC反应中原位制备纳米ZnO及其催化MDC分解制MDI的环境友好过程”，负责人。
3.河北省重大技术创新项目（12275603Z）：“对氨基苯酚清洁生产工艺与关键技术”，负责人。

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