精细化工

含硒/碲高分子

1. 在国际上率先制备了一系列主链、侧链以及超支化含硒嵌段共聚物，其自组装形成的聚集体具有灵敏的氧化还原响应性、伽玛射线以及红光响应性，从而发展了一类新型的生物高分子，有望成为化疗-放疗相结合的药物载体。
2. 在国际上首次报道了含碲高分子聚集体，其具有超灵敏的氧化响应性，提供了一类新的对ROS具有响应性的高分子材料。
3. 发现了一系列新型含硒动态共价键，为超分子组装提供新的推动力，有望用于制备可逆和再循环超分子材料和高分子材料。
4. 利用硒（碲）与金属的配位特性，将含硒（碲）高分子聚集体与金属进行配位，发展了新型的配位响应高分子载药体系，为与金属药物的协同治疗提供了新的途径。

代表性论文：
1. Tan, Y.; Dai, Y.; Zhao, P.; Liu, C.*;Xu, H.*: Modular 3D shape programming method for multiple substrates.Matter,2024,7, 1117.
2. He, C.; Liu, C.; Pan, S.; Tan, Y.; Guan, J.*;Xu, H.*;Polyurethane with β-Selenocarbonyl Structure Enabling the Combination of Plastic Degradation and Waste Upcycling.Angew. Chem. Int. Ed.2024,63, e202317558.
3. Xianyu, B.; Pan, S.; Gao, S.;Xu, H.*; Li, T.*; Selenium-Containing Nanocomplexes Achieve Dual Immune Checkpoint Blockade for NK Cell Reinvigoration.Small2023, 202306225.
4. Tan, Y.; Guan, J.;Xu, H.*; Hyper-stable cholesteric heliconical architectures for monochromatic light separation.Matter2023,6, 3121.
5. Chen, N.#; Li, S.#; Zhao, P.#; Liu, R.; Xie, Y.; Lin, J.; Nijhuis, C.; Xu, B.; Zhang, L.*;Xu, H.*; Li, Y.*: Extreme Long-Lifetime Self-Assembled Monolayer for Air-Stable Molecular Junctions.Sci. Adv.2023, 9, eadh3412.
6. Liu, C.#; Si, J.#; Cao, M.; Zhao, P.; Dai, Y.;Xu, H.*: Visualizing Chain Growth of Polytelluoxane via Polymerization Induced Emission.Adv. Sci.2023, 202304518.
7. Dai, Y.; Zhang, Z.; Daniels, M.; Bao, Y.; Guan, J.; Zhang, S.; Zhou, R.; Tan, Y; Liu, L.; Xiao, H.; Cui, S.;Xu, H.*; Polytelluoxane: A chalcogen polymer that bridges the gap between inorganic oxides and macromolecules.Chem2023,9, 2006.
8. Liu, C.; Xianyu, B.; Dai, Y.; Pan, S.; Li, T.;Xu, H.*; Intracellular Hyperbranched Polymerization for Circumventing Cancer Drug Resistance.ACS Nano.2023,17, 11905.
9. Dai, Y.; Guan, J.; Zhang, S.; Pan, S.; Xianyu, B.; Ge Z.; Si, J.; He, C.;Xu, H.*; Tellurium-containing Polymers: Recent Developments and Trends.Prog. Polym. Sci.2023,141,101678.
10. Pan, S.; Guan, J.; Xianyu, B.; Tan, Y.; Li, T.*;Xu, H.*:A Nanotherapeutic Strategy to Reverse NK Cell Exhaustion.Adv. Mater.,2023,35, 2211370.
11. Bai, B.; Qi, S.; Yang, K.; Yu, X.; Jian, R.; Zhang, T.; Wang, D.; Meng, H.; Zhao, Y.; Xia, Y.*;Xu, H.*; Yu, G.*; Chen, Z.*: Self-Assembly of Selenium-Doped Carbon Quantum Dots as Antioxidants for Hepatic Ischemia-Reperfusion Injury Management.Small,2023,19, 202300217.
12. Cao, M.; Tan, Y.;Xu, H.*: Mechanochemistry of dynamic chalcogen-containing polymers: a minireview.New Journal of Chemistry, 2023,47, 5582.
13. Li, X.; Yang, F.; Li, Y.; Liu, C.; Zhao, P.; Cao, Y.;Xu, H.*; Chen, Y.*: Diselenide as a Dual Functional Mechanophore Capable of Stress Self-reporting and Self-strengthening in Polyurethane Elastomers.CCS Chemistry,2023,5,925.
14. Si, J.; Zhao, P.; Guan, J.*; Ji, S.;Xu, H.*: Dynamic Fluorescent Patterning Based on Visible-light-responsive Diselenide Metathesis.Langmuir,2022, 38, 13272.
15. Zhao, P.; Cao, M.; Liu, C.; Dai, Y.; Tan, Y.; Ji, S.;Xu, H.*: Water-Enhanced and Remote Self-Healing Elastomers in Various Harsh Environments.ACS Appl. Mater. Interfaces,2022,14, 27413.
16. Liu, C.; Ji, S.*;Xu, H.*: Rapidly reprogrammable actuation of liquid crystal elastomers.Matter,2022,3, 2397.
17. Han, Y.; Liu, C.;Xu, H.*; Cao, Y.*: Engineering reversible hydrogels for 3D cell culture and release using diselenide catalyzed fast disulfide formation.Chin. J. Chem.2022,40, 1578.
18. He, C.; Cao, M.; Liu, J.; Ge, Z.; Zhou, R.;Xu, H.*: Nanotechnology in the Olympic Winter Games and Beyond.ACS Nano2022,16, 4981.
19. Zhang, L.; Dai, Y.; Pan, S.; Tan, Y.; Sun, C.; Cao, M.;Xu, H.*: Copper-Selenocysteine Quantum Dots for NIR-II Photothermally Enhanced Chemodynamic Therapy.ACS Appl. Bio. Mater.2022,5, 1794.
20. Cao, M.; Zhao, P.; Liu, C.; Xia, J.;Xu, H.*: When Dynamic Diselenide Bonds meet Dynamic Imine Bonds in Polymeric Materials.Macromol. Rapid Commun.2022,2200083.
21. Liu, C.; Tan, Y.;Xu, H.*: Functional Polymer Materials Based On Dynamic Covalent Chemistry.Science China Materials,2022,65, 2017.
22. Pan, S.; Li, T.; Tan, Y.;Xu, H.*:Selenium-containing Nanoparticles Synergistically Enhance Pemetrexed&NK Cell-Based Chemoimmunotherapy.Biomaterials,2022,280, 121321.
23. Zhao, P.; Xia, J.; Liu, J.; Tan, Y.; Ji, S.;Xu, H.*: Laser-Induced Remote Healing of Stretchable Diselenide-Containing Conductive Composites.ACS Appl. Mater. Interfaces,2021,13, 50422.
24. Liu, C.#; Tan, Y.#; He, C.; Ji, S.*;Xu, H.*: Unconstrained 3D Shape Programming with Light-Induced Stress Gradient.Adv. Mater.,2021,33, 2105194.
25. Zhang, L.; Sun, C.; Tan, Y.;Xu, H.*: Selenium-Sulfur-Doped Carbon Dots with Thioredoxin Reductase Activity.CCS Chem.,2021,3, 2249.
26. Dai, Y.; Li, T.; Zhang, Z.; Tan, Y.; Pan, S.; Zhang, L.;Xu, H.*: Oxidative Polymerization in Living Cells.J. Am. Chem. Soc.,2021,143, 10709.
27. Pan, S.;Xu, H.*:ROS-responsive Tellurium-containing Polymers.Acta Polymerica Sinica,2021,52,857.
28. Sun, C.; Gao, S.; Tan, Y.; Zhang, Z.;Xu, H.*: Side-Chain Selenium-Grafted Polymers Combining Antiangiogenesis Treatment with Photodynamic Therapy and Chemotherapy.ACS Biomater. Sci. Eng.,2021,7,3201.
29. Xia, J.;Xu, H.*:Selenium-containing Surface/interface Chemistry.Chemical Journal of Chinese Universities,2021,42, 997.
30. Chen, Q.; Yang, Y.; Yu, Y.;Xu, H.*:“Reprocessable Thermosets”: Synthesis and Characterization of Vitrimer in the Undergraduate Lab Course.J. Chem. Edu.,2021,98, 1429.
31. Yang, J.; Pan, S.; Gao, S.; Li, T.;Xu, H.*: CO/chemosensitization/antiangiogenesis Synergistic Therapy with H2O2-responsive Diselenide-containing Polymer.Biomaterials,2021,271, 120721.
32. Liu, C.#; Zhang, Z.#; Fan, Z.; He, C.; Tan, Y.;Xu, H.*: Adaptive Se-Te Metathesis Controlled by Cucurbituril-Based Host-Guest Interaction.Chem. Asian J.2020,15, 4321.
33. Zhao, P.; Xu, C.*; Sun, C.; Xia, J.; Sun, L.; Li, J.;Xu, H.*: Exploring the Difference of Bonding Strength Between Silver(I) and Chalcogenides in Block Copolymer Systems.Polym. Chem.2020,11, 7087.
34. Wu, Q.#; Yuan, Y.#; Chen, F.; Sun, C.;Xu, H.*;Chen, Y.*: Diselenide-Linked Polymers under Sonication.ACS Macro Lett.,2020,9, 1547.
35. Xia, J.; Tan, Y.;Xu, H.*: Selenium-containing Dynamic Covalent Polymers.Acta Polymerica Sinica,2020,51,1190.
36. Sun, C.; Tan, Y.;Xu, H.*: From Selenite to Diselenide-Containing Drug Delivery Systems.ACS Materials Lett.2020, 2, 1173.
37. Li, T.;Xu, H.*: Selenium-Containing Nanomaterials for Cancer Treatment.Cell Reports Physical Science,2020,1, 100111.
38. Yang, J.; Pan, S.; Gao, S.; Dai, Y.;Xu, H.*: Anti-recurrence/metastasis and Chemosensitization Therapy with Thioredoxin Reductase-interfering Drug Delivery System.Biomaterials,2020,249, 120054.
39. Dai, Y.; Zheng, K.; Tan, Y.; Xiang, W.; Xianyu, B.;Xu, H.*: Fischesserite-inspired Recyclable Se-Polyurethanes for Selective Gold Extraction.Advanced Sustainable Systems,2020,4, 2000072.
40. Pan, S.; Yang, J.; Ji, S.; Li, T.; Gao, S.; Sun C.;Xu, H.*; Cancer Therapy by Targeting Thioredoxin Reductase Based on Selenium-Containing Dynamic Covalent Bond.CCS Chem.,2020,2, 225.
41. Gao, S.; Li, T.; Guo, Y.; Sun, C.; Xianyu, B.;Xu, H.*: Selenium-Containing Nanoparticles Combine the NK Cells Mediated Immunotherapy with Radiotherapy and Chemotherapy.Adv. Mater.,2020, 1907568.
42. Liu, C.; Fan, Z., Tan, Y.; Fan, F.;Xu, H.*: Tunable Structural Color Patterns Based on the Visible-Light-Responsive Dynamic Diselenide Metathesis.Adv. Mater.,2020, 1907569.
43. Li, T.; Pan, S.; Zhuang, H.; Gao, S;Xu, H.*: Selenium-Containing Carrier-Free Assemblies with Aggregation-Induced Emission Property Combine Cancer Radiotherapy with Chemotherapy.ACS Appl. Bio Mater.,2020,3, 1283.
44. Zhao, P.; Xia, J.; Cao, M.;Xu, H.*: Wavelength-Controlled Light-Responsive Polymer Vesicle Based on Se–S Dynamic Chemistry.ACS Macro Lett.,2020,9, 163.
45. Li, T.; Pan, S.; Gao, S.*; Xiang, W.; Sun, C.; Cao, W.;Xu, H.*: Diselenide-Pemetrexed Assemblies for Combined Cancer Immuno-, Radio-, and Chemotherapies.Angew. Chem. Int. Ed.,2020,132, 2722.
46. Xia, J.; Li, H.*;Xu, H.*: Measuring the Strength of S/Se Based Dynamic Covalent Bonds.Acta Polym. Sin.,2020,2, 205.
47. Fan, Z.;Xu, H.*: Recent Progress in the Biological Applications of Reactive Oxygen Species-Responsive Polymers.Polym. Rev.2020,60, 114.
48. Sun, C.; Wang, L.; Xianyu, B.; Li, T.; Gao, S.*;Xu, H.*: Selenoxide Elimination Manipulate the Oxidative Stress to Improve the Antitumor Efficacy.Biomaterials,2019, 119514.
49. Cao, W.*;Xu, H.*: Selenium Containing Supra-amphiphiles.Mater. Chem. Front.,2019,3, 2010.
50. Fan, F.; Liu, C.; Wang, S.; Lv, J.; Li, W.*; Fu, Y.*;Xu, H.*: Swelling-Induced 3D Photopatterning on a Diselenide-Containing Elastomer.J. Mater. Chem. C2019,7, 10777.
51. Xia, J.; Zhao, P.; Pan, S.;Xu, H.*: Diselenide-Containing Polymeric Vesicles with Osmotic Pressure Response.ACS Macro Letters2019,8, 629.
52. Wang, L.; Zhu, K.; Cao, W.*; Sun, C.; Lu, C.;Xu, H.*: ROS-triggered Degradation of Selenide-containing Polymers Based on Selenoxide Elimination.Polym. Chem.2019,10, 2039.
53. Xiang, W.; Li, Z.; Xu, C.; Li, J.*; Zhang, W.*;Xu, H.*: Quantifying the Bonding Strength of Gold-chalcogen Bonds in Block Copolymer Systems.Chem. Asian J.2019,14, 1481.
54. Liu, C.; Xia, J.; Ji, S.; Fan, Z.;Xu, H.*: Visible-Light-Induced Metathesis Reaction between Diselenide and Ditelluride.Chem. Commun.,2019,55, 2813.
55. Xia, J.; Zhao, P.; Zheng, K.; Lu, C.; Yin, S.;Xu, H.*: Surface Modification Based on Diselenide Dynamic Chemistry: Towards Liquid Motion and Surface Bioconjugation.Angew. Chem. Int. Ed.,2019,58, 542.
56. Li, F.*; Yang, D.;Xu, H.*: Nonmetal Heteroatom Doped Carbon dots: Synthesis and Property.Chem. Eur. J.,2019,25, 1165.
57. Fan, F.; Ji, S.; Sun, C.; Liu, C.; Yu, Y.; Fu, Y.;Xu, H.*: Wavelength-Controlled Dynamic Metathesis: A Light-Driven Exchange Reaction Between Disulfide and Diselenide Bonds.Angew. Chem. Int. Ed.,2018,57, 16426.
58. Fan, F.; Gao, S.; Ji, S.; Fu, Y.*; Zhang, P.*;Xu, H.*:Gamma Radiation Responsive Side-chain Tellurium-containing Polymer for Cancer Therapy.Mater. Chem. Front.,2018,2, 2109.
59. Xia, J.; Li, T.; Lu, C.;Xu, H.*: Selenium-containing Polymer: Perspectives toward Diverse Applications in both Adaptive and Biomedical Materials.Macromolecules,2018,51, 7435.
60. Li, F.; Li, Y.; Yang, X.; Han, X.; Jiao, Y.; Wei, T.; Yang, D.;Xu, H.*; Nie, G.*: Highly Fluorescent Chiral N-S-Doped Carbon Dots from Cysteine: Affecting Cellular Energy Metabolism.Angew. Chem. Int. Ed.,2018,57, 2377. (VIP paper)
61. Li, T.; Xiang, W.; Li, F.;Xu, H.*: Self-assembly Regulated Anticancer Activity of Platinum Coordinated Selenomethionine.Biomaterials,2018,157, 17.
62. Li, F.; Li, T.; Han, X.; Zhuang, H.; Nie, G.; Xu, H.*: Nanomedicine Assembled by Coordinated Selenium-Platinum Complexes Can Selectively Induce Cytotoxicity in Cancer Cells by Targeting the Glutathione Antioxidant Defense System.ACS Biomaterials Science & Engineering,2018,4, 1954(Biomaterials Science and Engineering in China Special Issue)
63. Zhou, W.; Li, H.; Xia, B.; Ji, W.; Ji, S.; Zhang, W.; Huang, W.*; Huo, F.*;Xu, H.*: Selenium-functionalized Metal-Organic Frameworks for Enzyme Mimics.Nano Research,2018,11, 5761.
64. Ji, S.; Fan, F.; Sun, C.; Yu, Y.;Xu, H.*: Visible Light Induced Plasticity of Shape Memory Polymers.ACS Appl. Mater. Interfaces,2017,9, 33169.
65. Wang, L.; Wang, W.; Cao, W.;Xu, H.*: Multi-hierarchical Responsive Polymers: Stepwise Oxidation of a Selenium- and Tellurium-Containing Block Copolymer with Sensitivity to both Chemical and Electrochemical Stimuli.Polym. Chem.,2017,8, 4520.
66. Li, F.; Li, T.; Sun, C.; Xia, J.; Jiao, Y.;Xu, H.*: Selenium-Doped Carbon Quantum Dots (Se-CQDs) for Free Radical Scavenging.Angew. Chem. Int. Ed.,2017,56, 9910.
67. Xia, J.; Li, F.; Ji, S.;Xu, H.*: Selenium-functionalized Graphene Oxide that Can Modulate the Balance of Reactive Oxygen Species.ACS Appl. Mater. Interfaces,2017,9, 21413.
68. Li, F.; Li, T.; Sun, C.; Xia, J.;Xu, H.*: Near-Infrared Light Stimuli-responsive Synergistic Therapy Nanoplatforms Based on the Coordination of Tellurium-containing Block Polymer and Cisplatin for Cancer Treatment.Biomaterials,2017,133, 208.
69. Ji, S.; El Mard, H.; Smet, M.; Dehaen, W.;Xu, H.*: Selenium Containing Macrocycles: Transformation between Se-N/Se-S/SeSe Bonds.Sci. China Chem.,2017,60, 1191.
70. Sun, C.; Ji, S.; Li, F.*;Xu, H.*: Diselenide-Containing Hyperbranched Polymer with Light-Induced Cytotoxicity.ACS Appl. Mater. Interfaces,2017,9, 12924.
71. Zhou, W.; Wang, L.; Li, F.; Zhang, W.; Huang, W.*; Huo, F.*;Xu, H.*: Selenium-containing Polymer@metal-organic Frameworks Nanocomposites as an Efficient Multi-responsive Drug Delivery System.Adv. Funct. Mater.,2017,27, 1605465.
72. Xia, J.; Ji, S.;Xu, H.*: Diselenide Covalent Chemistry at the Interface: Stabilizing Asymmetric Diselenide-containing Polymer via Micelle Formation,Polym. Chem.,2016,7, 6708.
73. Cao, W.; Li, F.; Chen, R.;Xu, H.*: Tellurium-containing Nanoparticles for Controlled Delivery of Cisplatin Based on Coordination Interaction,RSC Adv.,2016,6, 94033.
74. Li, T.; Li, F.; Xiang, W.; Yi, Y.; Chen, Y.; Cheng, L.; Liu, Z.*;Xu., H.*: Selenium-containing Amphiphiles Reduced and Stabilized Gold Nanoparticles: Kill Cancer Cells via Reactive Oxygen Species,ACS Appl. Mater. Interfaces,2016,8, 22106.
75. Fan, F.; Wang, L.; Li, F.; Fu, Y.*;Xu, H.*: Stimuli-Responsive Layer-by-Layer Tellurium-Containing Polymer Films for the Combination of Chemotherapy and Photodynamic Therapy.ACS Appl. Mater. Interfaces,2016,8, 17004.
76. Wang, L.; Cao, W.;Xu, H.*: Tellurium-Containing Polymers: Towards Biomaterials and Optoelectronic Materials.ChemNanoMat, 2016,2, 479.
77. Ji, S.; Xia, J.;Xu, H.*: Dynamic Chemistry of Selenium: Se–N and Se–Se Dynamic Covalent Bonds in Polymeric Systems.ACS Macro Lett.,2016,5, 78.
78. Li, T.; Smet, M.; Dehaen, W. andXu, H.*: Selenium–Platinum Coordination Dendrimers with Controlled Anti-Cancer Activity.ACS Appl. Mater. Interfaces,2016,8, 3609.(“Applied Materials and Interfaces in China” Special Issue)
79. Cao, W.; Wang, L.;Xu, H.*: Selenium/tellurium Containing Polymer Materials in Nanobiotechnology.Nano Today,2015,10, 717.
80. Ji, S.; Cao, W.; Yu, Y. andXu, H.*: Visible-Light-Induced Self-Healing Diselenide-Containing Polyurethane Elastomer.Adv. Mater.,2015,27, 7740.
81. Wang L.; Fan F.; Cao W. andXu H.*: Ultra-sensitive ROS-responsive Coassemblies of Tellurium-Containing Molecules and Phospholipids,ACS Appl. Mater. Interfaces,2015,7, 16054.
82. Cao, W.; Gu, Y.; Li, T.;Xu, H.*: Ultra-sensitive ROS-responsive Tellurium-containing Polymers.Chem. Commun.,2015,51, 7069.
83. Fang, R.;Xu, H.*; Cao, W.; Yang, L.; Zhang, X.*: Reactive Oxygen Species (ROS)-responsive Tellurium-containing Hyperbranched Polymer.Polym. Chem.,2015,6, 2817.
84. Cao, W.; Wang, L.;Xu, H.*: Coordination Responsive Tellurium-containing Multilayer Film for Controlled Delivery.Chem. Commun.,2015,51, 5520.
85. Huang, X.; Fang, R.; Wang, D.; Wang, J.;Xu, H.*; Wang, Y.*; Zhang, X.: Tuning Polymeric Amphiphilicity via Se-N Interactions: towards One-step Double Emulsion for Highly Selective Enzyme Mimics.Small,2015,11, 1537.
86. Li, T.; Yi, Y.;Xu, H.*: Selenium-containing Coordinating Assemblies with Selective Anti-cancer Activity: the Control of Reactive Oxygen Species.Acta Chim. Sinica,2014,72, 1209.
87. Wang, L.; Cao, W.; Yi, Y.;Xu, H.*: Dual Redox Responsive Co-assemblies of Diselenide-containing Block Copolymers and Polymer Lipids.Langmuir,2014,30, 5628.
88. Ji, S.; Cao, W.; Yu, Y.;Xu, H.*: Dynamic Diselenide Bonds: Exchange Reaction Induced by Visible Light without Catalysis.Angew. Chem. Int. Ed.,2014,53, 6781.（Hot Paper）
89. Zeng, L.; Li, Y.; Li, T.; Cao, W.; Yi, Y.; Geng, W.; Sun, Z.*;Xu, H.*: Selenium-platinum Coordination Compounds as Novel Anticancer Drugs: Selectively Killing Cancer Cells via a ROS-mediated Apoptosis Route.Chem. Asian. J.,2014,9, 2295.
90. Cao, W.; Gu, Y.; Meineck, M.; Li, T.;Xu, H.*: Tellurium-containing Polymer Micelles: Competitive-Ligand-Regulated Coordination Responsive Systems.J. Am. Chem. Soc.,2014,136, 5132.
91. Cao, W.; Gu, Y.; Meineck, M.;Xu, H.*: The Combination of Chemotherapy and Radiotherapy towards More Efficient Drug Delivery.Chem. Asian. J.,2014,9, 48 (Invited Focus Review).
92. Ji, S.; Cao, W.;Xu, H.*: A ROS Eliminating Nanocomposite Film Fabricated from Diselenide-Containing Polymer Micelles.Part. Part. Syst. Charact.,2013,30, 1034.
93. Miao, X.; Cao, W.; Zeng, W.; Wang, J.; Gao, J.; Yang, C.; Kong, D.*;Xu, H.*; Wang, L.; Yang, Z.*: Switchable Catalytic Activity: Selenium-containing Peptides with Redox Controllable Self-assembly Property.Angew. Chem. Int. Ed.,2013,52, 7781.
94. Ren, H.; Wu, Y.; Li, Y.; Cao, W.; Sun, Z.*;Xu, H.*; Zhang, X.: Visible Light Induced Disruption of Diselenide-Containing LbL Films: Toward Combination of Chemotherapy and Photodynamic Therapy.Small,2013,9, 3981.
95. Yi, Y.;Xu, H.*; Wang, L.; Cao, W.; Zhang, X.*: A Novel Dynamic Covalent Bond of Se-N: Towards Controlled Self-Assembly and Disassembly.Chem. Eur. J.,2013,19, 9506.
96. Cao, W.; Zhang, X.; Miao, X.; Yang, Z.*;Xu, H.*: Gamma-ray Responsive Supramolecular Hydrogel Based on Diselenide-containing Polymer and Peptide.Angew. Chem. Int. Ed.,2013,52, 6233.
97.Xu, H.*; Cao, W.; Zhang, X.*: Selenium-containing Polymers: Promising Biomaterials for Controlled Release and Enzyme Mimics.Acc. Chem. Res.,2013,46, 1647.
98.Xu, H.*; Chen, D.; Wang, S.; Zhou, Y.; Sun, J.; Zhang, W.; Zhang, X.*: Macromolecular Self-Assembly and Nanotechnology in China.Phil.Trans. R. Soc. A,2013,371, 20120305.
99. Han, P.; Li, S.; Cao, W.; Li, Y.; Sun, Z.; Wang, Z.;Xu, H.*: Red Light Responsive Diselenide-containing Block Copolymer Micelles.J. Mater. Chem. B,2013,1, 740.
100. Cao, W.; Li, Y.; Yi, Y.; Ji, S.; Zeng, L.; Sun, Z.*;Xu, H.*: Coordination-Responsive Selenium-Containing Polymer Micelles for Controlled Drug Release.Chem. Sci.,2012,3, 3403.
101. Yi, Y.; Fa, S.; Cao, W.; Zeng, L.; Wang, M.;Xu, H.*;Zhang, X.: Fabrication of Well-Defined Crystalline Azacalixarene Nanosheets Assisted by Se•••N Non-Covalent Interaction.Chem. Commun.,2012,48, 7495.
102. Li, S.; Han, P.;Xu, H.*: Self-healing Polymeric Materials. (in Chinese)Progress in Chemistry,2012,24, 1346.
103. Fu, Y.; Chen, J.;Xu, H.*; Van Oosterwijck, C.; Zhang, X.; Dehaen, W.; Smet, M.*: Fully-branched Hyperbranched Polymers with Diselenide Core as Glutathione Peroxidase Mimics.Macromol. Rapid Commun.,2012,33, 798. (Invited for Special Issue of“Polymer Science: the Next Generation”)
104.Xu, H.*; Schönhoff, M.; Zhang, X.: Unconventional Layer-by-Layer Assembly: Surface Molecular Imprinting and Its Applications.Small,2012,8, 517.
105. Ren, H.; Wu, Y.; Ma, N.;Xu, H.*; Zhang, X.: Side-chain Selenium-Containing Amphiphilic Block Copolymers: Redox-Controlled Self-Assembly and Disassembly.Soft Matter,2012,8, 1460. (Top ten most-read Soft Matter articles in December, 2011)
106. Ma, N.;Xu, H.*; An, L.; Li, J.; Sun, Z.; Zhang, X.*: Radiation-Sensitive Diselenide Block Copolymer Micellar Aggregates: Toward the Combination of Radiotherapy and Chemotherapy.Langmuir,2011,27, 5874.
107. Han, P.; Ma, N.; Ren, H.;Xu, H.*; Li, Z.; Wang, Z.*; Zhang, X.: Oxidation-Responsive Micelles Based on a Selenium-Containing Polymeric Superamphiphile.Langmuir,2010,26, 14414.
108. Ma, N.; Li, Y.; Ren, H.;Xu, H.*; Li, Z.; Zhang, X.*: Selenium-containing Block Copolymers and Their Oxidation-responsive Aggregates.Polym. Chem.,2010,1, 1609. (Front cover page)
109. Liu, Z.; Yi, Y.;Xu, H.*; Zhang, X.; Ngo, T. H.; Smet, M.: Cation Selective Microcontact Printing Based on Surface Molecular Imprinted Layer-by-Layer Film.Adv. Mater.,2010,22, 2689. (Highlighted by NPG Asia Materials)
110. Gao, J.; Liu, Y.;Xu, H.*; Wang, Z.; Zhang, X.*: Biostructure-like Surfaces with Thermally Responsive Wettability Prepared by Temperature Induced Phase Separation Micro-molding.Langmuir,2010,26, 9673.
111. Ma, N.; Li, Y.;Xu, H.*; Wang, Z.; Zhang, X.*: Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers.J. Am. Chem. Soc.,2010,132, 442.
112.Xu, H.*;Huskens, J.*: Versatile Stamps in Microcontact Printing: Transferring Inks by Molecular Recognition and from Ink Reservoirs.Chem. Eur. J.,2010,16, 2342.
113.Xu, H.*; Gomez-Casado, A.; Liu, Z.; Reinhoudt, D. N.; Lammertink, R. G. H.*; Huskens, J.*: Porous Multilayer-Coated PDMS Stamps for Protein Printing.Langmuir,2009,25, 13972.
114. Wang, Y.;Xu, H.; Zhang, X.*: Tuning the Amphiphilicity of Building Blocks: Controlled Self-assembly and Disassembly for Functional Supramolecular Materials.Adv. Mater.,2009,21, 2849.
115. Gao, J.; Liu, Y.;Xu, H.*; Wang, Z.; Zhang, X.*: Mimicking Biological Structured Surfaces by Phase Separation Micromolding.Langmuir,2009,25, 4365.
116.Xu, H.; Ling, X.; van Bennekom, J.; Duan, X.; Ludden, M. J. W.; Reindoudt, D. N.; Wessling, M.; Lammertink, R. G. H.*; Huskens, J.*: Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stamps.J. Am. Chem. Soc.,2009,131, 797.
117.Xu, H.; Wang, Y.; Wang, Z.*; Liu, J.; Smet, M.*; Dehaen, W.: Dendritic Tellurides Act as Antioxidant.Chinese Science Bulletin,2006, 51, 2315.
118.Xu, H.; Gao, J.; Wang, Y.; Wang, Z.; Smet, M.*; Dehaen, W.; Zhang, X.*:Hyperbranched Polyselenides as Glutathione Peroxidase Mimics.Chem. Commun.,2006, 796.
119. Zhang, X.*;Xu, H.; Dong, Z.; Wang, Y.; Liu, J.*; Shen, J.:Highly Efficient Dendrimer-Based Mimic of Glutathione Peroxidase.J. Am. Chem. Soc.,2004,126, 10556. (Highlighted by ACS Heart Cut)